AC Stark shift in a 3 level system

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SUMMARY

The discussion focuses on the AC Stark shift in a three-level quantum system characterized by energy levels E1, E2, and E3, where E1 < E2 << E3. The user correctly identifies the formula for the AC Stark shift as EStark = (Ω²ω)/(2(ω² - ω0²)), with Ω representing the Rabi frequency between E2 and E3. The analysis concludes that the resonant frequency shifts to ω0 - (Ω²)/(2ω) due to the coupling of E2 and E3, while E1 remains uncoupled, affirming the validity of the calculations under first-order perturbation theory.

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  • Understanding of quantum mechanics and energy level systems
  • Familiarity with the AC Stark effect and perturbation theory
  • Knowledge of Rabi frequency and its implications in quantum systems
  • Experience with Voigt profile fitting in spectroscopy
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  • Study the implications of the AC Stark effect in multi-level quantum systems
  • Learn about perturbation theory in quantum mechanics
  • Explore the mathematical derivation of the Voigt profile in spectroscopy
  • Investigate the effects of electric dipole approximation in quantum transitions
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Quantum physicists, researchers in atomic and molecular physics, and anyone studying the effects of electric fields on multi-level quantum systems will benefit from this discussion.

BillKet
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Hello! I want to make sure I got this right. Say we have a 3 level system ordered such that ##E_1<E_2<<E_3## with ##\omega_0 = E_2-E_1##. I use a laser to measure ##\omega_0## (e.g. I scan the laser frequency across the expected location of the resonance and fit that with a Voigt profile, we can ignore any systematic effects of the measurement). If I had just a 2 level system, the center of the peak would be exactly at ##\omega_0##. Now, let's say that the electric field can also couple ##E_2## and ##E_3## (but ##E_1## and ##E_3## can't be coupled in the electric dipole approximation). The formula for the AC Stark shift in this case is given by

$$E_{\mathrm{Stark}} = \frac{\Omega^2\omega}{2(\omega^2-\omega_0^2)}$$

where ##\Omega## is the Rabi frequency of the field between ##E_2## and ##E_3## and ##\omega = E_3-E_2##. In our limit this becomes:

$$E_{\mathrm{Stark}} = \frac{\Omega^2}{2\omega}$$
So the ##E_2## levels gets pushed down (towards the ##E_1##) by this amount. So the resonant frequency in this case will appear to be at:

$$\omega_0-\frac{\Omega^2}{2\omega}$$

Is this right (at least to first order in perturbation theory as the 2 pair of levels are treated independently)? Thank you!
 

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