Adiabatic compression of ideal diatomic gas

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SUMMARY

An ideal diatomic gas undergoes adiabatic compression from an initial pressure of 1.9 atm and volume of 0.30 m3 to a final pressure of 2.9 atm. The work done by the gas during this process is calculated to be -185 kJ, indicating that the gas does work on the surroundings. The relevant equations used include the adiabatic condition PVγ = constant, with γ = 7/5 for diatomic gases. The method for calculating work involves integrating pressure with respect to volume and applying the ideal gas law.

PREREQUISITES
  • Understanding of adiabatic processes in thermodynamics
  • Familiarity with the ideal gas law and its applications
  • Knowledge of specific heat ratios, particularly for diatomic gases
  • Ability to perform calculus-based integration for work calculations
NEXT STEPS
  • Study the derivation and application of the adiabatic condition PVγ = constant
  • Learn about the relationship between internal energy change and work done in adiabatic processes
  • Explore the implications of the first law of thermodynamics in adiabatic systems
  • Investigate the use of the ideal gas law in various thermodynamic cycles
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This discussion is beneficial for physics students, particularly those studying thermodynamics, as well as engineers and scientists working with gas dynamics and energy systems.

Fizz_Geek
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Homework Statement



An ideal diatomic gas, with rotation but no oscillation, undergoes an adiabatic compression. Its initial pressure and volume are 1.9 atm and 0.30 m3. It's final pressure is 2.9 atm. How much work is done by the gas?

P0 = 1.9 atm = 1.93e5 Pa
V0 = 0.30 m3
P = 2.9 atm = 2.94e5 Pa

Homework Equations



PVγ=P0V0γ

Where γ = CP/CV

And for an ideal diatomic gas, we have:

γ=\frac{7}{5}

The Attempt at a Solution



W = \intP dV
= \int P0(V0/V)\frac{7}{5} dV
= P0V0\frac{7}{5}(V\frac{-2}{5}-V0\frac{-2}{5})/(\frac{-2}{5})

Then we can solve for V from the adiabatic condition, since we were given the final pressure:

PVγ=P0V0γ

Plugging in the values, I get:

V = 0.22 m3

Then, plugging this value into the work equation, I get:

W = -1.85e5 J or 185 kJ of work done by the gas.

Sorry about my notation, I'm new to LaTex. So, did I do this right?

Thanks in advance.
 
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I did not get your answer.

But if I may:

pVγ = c = p1V1γ

W = ∫pdV = ∫(c/Vγ)dV = c∫VdV with your limits (I also got V2 = 0.22).

Also, the work done BY the gas must be a negative number.
 
Last edited:
That's what I was trying to do, but my calculator died, so I was using the graphing calculator app on my phone.

Did you get c = 3.577e4 ?

Then W = - 19 kJ ?

If not, can you just tell me if the method is correct or not? Did I use the right value of gamma and the right equations?

Thanks again!
 
Fizz_Geek said:
That's what I was trying to do, but my calculator died, so I was using the graphing calculator app on my phone.

Did you get c = 3.577e4 ? Yes.

Then W = - 19 kJ ? Yes!

If not, can you just tell me if the method is correct or not? Did I use the right value of gamma and the right equations?

Thanks again!
EDIT:
see above .
You did fine, it was my goof.

I didn't double-check you value of γ though.
 
Last edited:
Oh! Thanks very much for your time!
 
There is an easier way to do this using TV^{(\gamma-1)} = PV^{\gamma}/nR = \text{constant} to find an expression for ΔT and then use \Delta U = nC_v\Delta T = W (adiabatic) to find W.

AM
 
Last edited:
Andrew Mason said:
There is an easier way to do this using TV^{(\gamma-1)} = PV^{\gamma}/nR = \text{constant} to find the change in temperature and then \Delta U = nC_v\Delta T = W (adiabatic) to find W.

AM

I didn't think ΔU = CVdT was covered in an intro physics course, then I found it in my Resnick & Halliday ... :redface:

Good thought!
 
Last edited:
Actually, that formula is in my intro book. But how would I use it here? I don't have the value of n.
 
Fizz_Geek said:
Actually, that formula is in my intro book. But how would I use it here? I don't have the value of n.

Don't need it.

T1 = p1V1/nR
T2 = p2V2/nR
ΔT = T2 - T1 = (1/n)(p2V2 - p1V1)/R
ΔU = ncvΔT = W; the n 's cancel out.
cv is the molar specific heat at const. volume. R is the universal gas constant.
 
Last edited:
  • #10
Oh! Okay, thanks for all your help!
 

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