Alcohol gel cooled with dry ice

Click For Summary

Discussion Overview

The discussion centers around the phenomenon observed when cooling 91% isopropyl alcohol with dry ice, specifically the formation of a thick gel. Participants explore the underlying mechanisms, including the role of water content and intermolecular forces, while questioning the definitions and characteristics of gels.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant observed that the alcohol became a thick gel when cooled with dry ice and sought to understand the underlying process.
  • Another participant noted a slight increase in volume upon returning to room temperature, complicating the measurement due to CO2 gas bubbles.
  • One hypothesis proposed is that the 9% water content in the alcohol contributes to the gelling rather than solidifying.
  • A participant questioned whether dry ice could extract water from the solution, suggesting that intermolecular forces might be involved at low temperatures.
  • It was mentioned that intermolecular forces are responsible for both gelling and solidifying, as well as maintaining the liquid state.
  • Another participant inquired about the role of hydrogen bonds from the alcohol group and expressed uncertainty about the technical definition of a gel, noting the absence of the Tyndall effect and the gel's behavior when poured.

Areas of Agreement / Disagreement

Participants express various hypotheses regarding the gelling process and the role of intermolecular forces, but no consensus is reached on the exact mechanisms or definitions involved.

Contextual Notes

Participants acknowledge limitations in their understanding of gels and the specific conditions under which the observations were made, including temperature measurements and the presence of gas bubbles.

mishima
Messages
576
Reaction score
43
Hi I tried cooling down some 91% isopropyl alcohol with dry ice. After a few minutes, the alcohol became a thick gel. I am wondering what is going on there, thanks.
 
Chemistry news on Phys.org
I mean why does it become gel? I tried putting some in a graduated cylinder and only noticed a slight (1mL) increase in volume after it returned to room temperature. However it also contained a great deal of CO2 gas bubbles making the cold reading difficult.
 
Perhaps 9% of water is what makes it gelling instead of nicely solidifying.
 
I'm not sure, dry ice gets a shell/coating of water ice when submerged in water. Could it extract the 9% from solution? I wasn't specifically looking for such a shell so I don't know if that happens/is possible. I was thinking intermolecular forces might be coming into play at the low temperature.
 
No doubt about intermolecular forces playing their part - but they are responsible both for gelling and for solidifying (actually they are also responsible for keeping liquid in place).
 
Do you think its the hydrogen bonds coming off the alcohol group, specifically?

I actually don't know the technical definition of a gel, I thought it was like a colloid but I did not see the Tyndall effect. I don't think it was quite viscous enough to stay put in an inverted cup, it bubbled violently and evaporated rapidly when poured on a room temperature surface. It was below range of both my non-contact thermometer and my normal alcohol thermometer, but I assume close to the temperature of dry ice.
 

Similar threads

Replies
11
Views
3K
  • · Replies 131 ·
5
Replies
131
Views
10K
  • · Replies 11 ·
Replies
11
Views
7K
Replies
11
Views
5K
  • · Replies 3 ·
Replies
3
Views
4K
  • · Replies 2 ·
Replies
2
Views
2K
Replies
18
Views
3K
Replies
1
Views
2K
  • · Replies 9 ·
Replies
9
Views
3K
Replies
7
Views
3K