Aluminium oxide surface and conductivity?

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Discussion Overview

The discussion revolves around the conductivity of aluminium surfaces, specifically focusing on the thin aluminium oxide layer that typically protects these surfaces. Participants explore the implications of this oxide layer on electrical measurements, particularly contact resistance, and the conditions under which it may or may not conduct electricity.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • Some participants note that the aluminium oxide layer is generally considered non-conductive, yet they observe small contact resistance when measuring with a multimeter, raising questions about the layer's integrity or conductivity.
  • One participant suggests that the oxide layer is extremely thin, with breakdown voltages within the range of typical multimeter measurements, potentially allowing for conduction under certain conditions.
  • Another participant proposes a method to test the resistance of the aluminium oxide layer using a low voltage and a series resistor, indicating that the results could vary based on the current range of the multimeter used.
  • A participant shares experimental results showing a consistent contact resistance of 2Ω across a range of currents, suggesting linear behavior and questioning the presence of a breakdown voltage or hysteresis in their setup.
  • There is mention of using identical electrodes to eliminate electrochemical effects, which may influence the observed resistance values.

Areas of Agreement / Disagreement

Participants express differing views on the conductivity of the aluminium oxide layer and the factors influencing contact resistance. The discussion remains unresolved, with multiple competing perspectives on the nature of the oxide layer and its effects on electrical measurements.

Contextual Notes

Limitations include the dependence on the specific conditions of the experiments conducted, such as the thickness of the oxide layer, the voltage applied, and the type of electrodes used. There are also unresolved questions regarding the breakdown voltage and its implications for conductivity.

spareine
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Aluminium surfaces are protected by a thin aluminium oxide layer. The oxide layer supposedly does not conduct electricity. However, when measuring the contact resistance between the test pen of a multimeter and the aluminium, this resistance is always small. Why? Is the oxide layer easily punctured?
 
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spareine said:
Aluminium surfaces are protected by a thin aluminium oxide layer. The oxide layer supposedly does not conduct electricity. However, when measuring the contact resistance between the test pen of a multimeter and the aluminium, this resistance is always small. Why? Is the oxide layer easily punctured?
The oxide layer is extremely thin, typically up to about https://www.surrey.ac.uk/mes/files/Castle_paper2.pdf. For such thin layers, the breakdown voltage is well within the voltage range that a multimeter can reach (for example a breakdown voltage of 6V is reported http://photonics-benelux.org/proc08/s08p195.pdf for a 10nm crystalline sample)
 
spareine said:
Aluminium surfaces are protected by a thin aluminium oxide layer. The oxide layer supposedly does not conduct electricity. However, when measuring the contact resistance between the test pen of a multimeter and the aluminium, this resistance is always small. Why? Is the oxide layer easily punctured?
What is the smallest current range on your multimeter?

If you use a1.5v battery and a series resistor (for example, 150k ohm to limit current to 10uA), then connect these in series with the aluminium and your meter (set to measure current, 10uA FSD) you can test its resistance at this lower voltage. Let us know what you find.
 
I examined the contact resistance of aluminium foil on aluminium foil (4 cm2) with a voltmeter, an amperemeter, and a variable voltage power supply. Results: the contact resistance was 2Ω for the entire current range from 1 to 100 mA (voltage range 2 - 200 mV). Linear behavior, constant resistance value, no threshold ('breakdown voltage') or hysteresis.

I used identical electrodes of aluminium foil to exclude electrochemical effects. (Anyway, repeating the experiment with a steel point on aluminium foil resulted in a similar ohmic contact resistance, of the same order of magnitude as 2Ω.)
 
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