An experiment against the second law of thermodynamics

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SUMMARY

The discussion centers on the proposal of using a resistor, diode, and battery to convert thermal energy into chemical energy, questioning whether this process violates the second law of thermodynamics. Participants clarify that this concept resembles a perpetual motion machine, which is impossible according to thermodynamic principles. Key points include the misunderstanding of resistors, the role of thermal noise, and the implications of using ideal components like perfect diodes. The consensus is that energy cannot be extracted from thermal noise without violating established thermodynamic laws.

PREREQUISITES
  • Understanding of the second law of thermodynamics
  • Familiarity with resistor and diode functions
  • Knowledge of thermal noise and its implications in circuits
  • Basic principles of heat engines and energy conversion
NEXT STEPS
  • Research the implications of Nyquist noise in electrical circuits
  • Study the Thevenin model of resistors and its applications
  • Explore the concept of Maxwell's Demon and its relation to thermodynamics
  • Investigate the characteristics of ideal diodes and their theoretical limits
USEFUL FOR

Physicists, electrical engineers, and students of thermodynamics seeking to understand the limitations of energy conversion systems and the principles governing thermal energy and electrical circuits.

  • #31
Philip Koeck said:
I would say this "semi mirror" doesn't even have to be perfect as you describe it.
Any "passive" mirror that transmits a bit more in one direction and reflects a bit more in the other should be in conflict with the 2nd law.

By "passive" I mean that it doesn't require energy input.

If you just imagine two large, plane surfaces at the same temperature and then you put such a mirror between them the one surface would heat up and the other would cool down.

Do you agree?
If the semi-mirror were imperfect (absorbed some fraction of the radiation impinging on it) then the concern would arise about how it would re-emit that radiation. So now we have that complexity to contend with.
 
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  • #32
jbriggs444 said:
If the semi-mirror were imperfect (absorbed some fraction of the radiation impinging on it) then the concern would arise about how it would re-emit that radiation. So now we have that complexity to contend with.
I agree. That's why I only considered transmission and reflection. The semi-mirror shouldn't absorb.
 
  • #33
If you require V to be identically zero, you require the thermal noise to be zero as well, i.e. T = 0.

If you have a resistor at T > 0 and a diode at T = 0, you have a heat engine. Of course you can extract work.
 
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  • #34
Thank you for your answer.
I agree, but just ##V=0## is not enough to extract work. It's a combination of ##V=0## and ##I=0## that extracts work.
Is it correct that ability to extract work from thermal noise contradicts to the second law of thermodynamics?

And one more question, sorry. Does superconductor produce thermal noise? If it doesn't then we have one half of prefect diode and ##T>0 ##. Probably somebody else could figure out how to create the other half of perfect diode :).
 
  • #35
Again, you are discussing a heat engine. You extract work by having part of it at one temperature and part at another. The fact that the components are electrical and not mechanical is irrelevant.

Imagining one part kept at absolute zero, even implicitly, gets you a Perpetual Motion Machine. We do not discuss these here, but armies of people have tried to make them, and have them "almost work - as soon as I get this last part right."
 
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  • #36
Vanadium 50 said:
Again, you are discussing a heat engine. You extract work by having part of it at one temperature and part at another. The fact that the components are electrical and not mechanical is irrelevant.

Imagining one part kept at absolute zero, even implicitly, gets you a Perpetual Motion Machine. We do not discuss these here, but armies of people have tried to make them, and have them "almost work - as soon as I get this last part right."
I'm sorry, probably I was not able to ask question properly. I didn't want to suggest Perpetual Motion Machine. I wanted to ask - is it possible to determine which volt-ampere characteristics are allowed by 2nd law of thermodynamics and which are not?
 
  • #37
lerus said:
is it possible to determine which volt-ampere characteristics are allowed by 2nd law of thermodynamics and which are not?
For the third time, no. Voltage and current are not the only two relevant quantities. Temperature is as well. You cannot sensibly discuss thermodynamics and ignore temperature.
 
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  • #38
Vanadium 50 said:
For the third time, no. Voltage and current are not the only two relevant quantities. Temperature is as well. You cannot sensibly discuss thermodynamics and ignore temperature.
Thank you, I think I understood at last. Energy will flow from hotter body to colder, as it should.
If temperature of one of the bodies is ##0##, this body will be able to extract energy from any other body. It means that we created Perpetual Motion Machine, which is not possible.
Thank you for being so patient.
 

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