Analytical Chemistry involving buffer

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SUMMARY

The discussion centers on calculating the volume of 0.200M HCl required to create a buffer solution with a pH of 3.37 from 250.0ml of 0.300M sodium mandelate. Participants confirm the use of the Henderson-Hasselbalch equation, pH = pKa + log [A-/HA], while addressing the complete dissociation of HCl and its role in protonating sodium mandelate. The assumption is made that the protonation occurs stoichiometrically, allowing for the determination of the necessary HCl volume.

PREREQUISITES
  • Understanding of buffer solutions and their pH calculations
  • Familiarity with the Henderson-Hasselbalch equation
  • Knowledge of acid-base dissociation and stoichiometry
  • Basic concepts of molarity and solution preparation
NEXT STEPS
  • Research the Henderson-Hasselbalch equation in detail
  • Study the dissociation constants (Ka) of weak acids and their conjugate bases
  • Learn about stoichiometric calculations in acid-base reactions
  • Explore practical applications of buffer solutions in analytical chemistry
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Chemistry students, analytical chemists, and anyone involved in buffer solution preparation and pH management in laboratory settings.

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Homework Statement



What volume of 0.200M HCl must be added to 250.0ml of 0.300M sodium mandelate to produce a buffer solution with a pH of 3.37?


Homework Equations


The Attempt at a Solution



For 2 and 3, can I use the equation pH = pKa + log [A-/HA]? but for HCl isn't that 100% disassociation? How can we use that if the Ka is not a given value for HCl?

Thanks.
 
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You are correct... Think of the HCl being used only to protonate a portion of the sodium mandelate.
 
And assume this protonation is stoichiometric.
 

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