Are P and E fields in LIH dielectric in dynamic equilibrium

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Discussion Overview

The discussion revolves around the relationship between the electric field (E), polarization (P), and electric displacement (D) in lithium hydride (LIH) dielectrics, particularly in the context of whether these quantities achieve a dynamic equilibrium when subjected to an external electric field. Participants explore theoretical implications and practical applications, referencing concepts from electrodynamics.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant asserts that polarization P is proportional to the net electric field inside the dielectric, as expressed by the equations P = ε0χeE and D = εE.
  • Another participant argues that while P and E are related, the equilibrium is static rather than dynamic, as both quantities do not change over time.
  • It is noted that the relationship between D and E0 is not straightforward, as D is defined by D = ε0E + P, which incorporates both E and P.
  • Participants discuss the implications of the equation ∫D·dA = Qfenc, suggesting that D must relate to the applied field due to its role as flux density of free charge.
  • One participant mentions that the relationship between D and E0 is complicated by the presence of a solenoidal field, which is influenced by the arrangement of free charges and dielectric materials.
  • There is a query about whether D and E0 can be considered interchangeable in certain scenarios, such as in a parallel plate capacitor, prompting clarification that they are not simply related.
  • It is clarified that in a parallel plate capacitor, D = ε0E0, with ε0 representing the permittivity of vacuum, not the dielectric.

Areas of Agreement / Disagreement

Participants express differing views on the nature of the equilibrium between E and P, with some suggesting it is static while others imply a dynamic aspect. There is no consensus on the interchangeability of D and E0, as participants highlight the complexities involved in their relationship.

Contextual Notes

The discussion reveals limitations in understanding the relationships between E, P, and D, particularly regarding the assumptions about static versus dynamic conditions and the influence of free charge arrangements on these fields.

sigma_
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If we know that the Polarization P in LIH dielectrics is proportional to the net field inside the dielectric according to:

P = ε0χeE...(1)

And we know that

D = εE...(2)

Does it not follow that we can ascertain the polarization directly from the applied (free charge) field, since we can relate D to E, and then E to P?

The author of my electrodynamics text (Griffiths), says that we cannot. His explanation being that once we place dielectric in an external field E0, the material will polarize and create an opposing field to the applied field, which in turn modifies the polarization again because it changes the total field that the atoms/molecules in the material are being subject to, and this process repeats over and over. In actuality, are these two quantities (E and P) in some sort of dynamic equilibrium within the material? If so, how come (1) and (2) are valid?
 
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sigma_ said:
...In actuality, are these two quantities (E and P) in some sort of dynamic equilibrium within the material?...
Yes, only the equilibrium is more appropriately called static (##\mathbf E##,##\mathbf P## are do not change in time).

If so, how come (1) and (2) are valid?

They both state the same thing: the polarization ##\mathbf P## is proportional to ##\mathbf E##.

Does it not follow that we can ascertain the polarization directly from the applied (free charge) field, since we can relate D to E, and then E to P?

You seem to think that ##\mathbf D## is somehow simply related to applied field ##\mathbf E_0##. In general, it is not! ##\mathbf D## is defined by

$$
\mathbf D = \epsilon_0 \mathbf E + \mathbf P,
$$

which contains both ##\mathbf E, \mathbf P##, the "quantities in mutual equilibrium". There is no simple relation of ##\mathbf D## to ##\mathbf E_0##, except inside a parallel plate capacitor, where ##\mathbf D = \epsilon_0 \mathbf E_0##.
 
Jano L. said:
Yes, only the equilibrium is more appropriately called static (##\mathbf E##,##\mathbf P## are do not change in time).
They both state the same thing: the polarization ##\mathbf P## is proportional to ##\mathbf E##.
You seem to think that ##\mathbf D## is somehow simply related to applied field ##\mathbf E_0##. In general, it is not! ##\mathbf D## is defined by

$$
\mathbf D = \epsilon_0 \mathbf E + \mathbf P,
$$

which contains both ##\mathbf E, \mathbf P##, the "quantities in mutual equilibrium". There is no simple relation of ##\mathbf D## to ##\mathbf E_0##, except inside a parallel plate capacitor, where ##\mathbf D = \epsilon_0 \mathbf E_0##.
Thanks for the reply, Jano!

We also know, however, that

∫D.dA = Qfenc

so D has to somehow be related to the applied field, because it is the flux density of the free charge, and typically free charge is what we control, and create (apply) fields with.

I think maybe my interpretation of D is incorrect here then?
 
Last edited:
Both ##\mathbf D## and ##\mathbf E_0## due to free charges satisfy the same equation you wrote above, but that is not sufficient to establish simple relation between them. This is because it is just one equation and we deal with vectors, which have three components. The two quantities are different from each other by third vector field that has every surface integral zero. Such field is called solenoidal field, and can be very complicated. It will be determined by the arrangement of the free charges with density ##\rho_{free}## and the dielectric bodies. ##\mathbf D ## at all points of the system can be found out from ##\rho_{free}##, but knowledge of ##\mathbf E_0## won't help much; I think one would do better with some energy minimization method that takes into account the spatial dependence of ##\epsilon##.
 
Jano L. said:
Both ##\mathbf D## and ##\mathbf E_0## due to free charges satisfy the same equation you wrote above, but that is not sufficient to establish simple relation between them. This is because it is just one equation and we deal with vectors, which have three components. The two quantities are different from each other by third vector field that has every surface integral zero. Such field is called solenoidal field, and can be very complicated. It will be determined by the arrangement of the free charges with density ##\rho_{free}## and the dielectric bodies. ##\mathbf D ## at all points of the system can be found out from ##\rho_{free}##, but knowledge of ##\mathbf E_0## won't help much; I think one would do better with some energy minimization method that takes into account the spatial dependence of ##\epsilon##.
So in the scenario I listed above, ##\mathbf D## and ##\mathbf E_0## are interchangable as long as a factor of ##\epsilon## is accounted for?
 
What do you mean by "interchangeable" ? They are not in simple relation one to another. What is your scenario concretely?
 
Jano L. said:
What do you mean by "interchangeable" ? They are not in simple relation one to another. What is your scenario concretely?
Let's say, for instance, an LIH dielectric between the plates of a parallel plate capacitor.
 
In parallel plate capacitor, ##\mathbf D = \epsilon_0 \mathbf E_0## where ##\mathbf E_0## is the field due to free charges. The factor ##\epsilon_0## is permittivity of vacuum, not of the dielectric.
 
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Jano L. said:
In parallel plate capacitor, ##\mathbf D = \epsilon_0 \mathbf E_0## where ##\mathbf E_0## is the field due to free charges. The factor ##\epsilon_0## is permittivity of vacuum, not of the dielectric.
Thank you very much for your help!
 

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