Atoms: How Many Protons, Neutrons & Electrons?

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Discussion Overview

The discussion revolves around the composition of atoms, specifically the number of protons, neutrons, and electrons in various elements, as well as the behavior of gases under different conditions. Participants explore both theoretical reasoning and experimental evidence related to atomic structure and gas laws.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant questions how we know the specific number of protons, neutrons, and electrons in elements like hydrogen and lithium, suggesting a mix of reasoning and experimental data.
  • Another participant confirms that gases at standard temperature and pressure (STP) occupy the same volume, but there is a correction regarding the volume of water, which is not a gas at STP.
  • It is noted that the number of protons and neutrons in nucleons has been determined experimentally.
  • A participant inquires about the methods used to determine the exact number of electrons in atoms.
  • Photoelectron spectroscopy is mentioned as a technique used to study electron configurations, particularly in lighter elements.
  • Several participants express curiosity about the principle that equal volumes of different gases contain the same number of particles, with some suggesting stoichiometry and others emphasizing the experimental basis for this concept.
  • One participant argues that the proof of gas behavior is based on experimental observations rather than purely theoretical derivations.

Areas of Agreement / Disagreement

Participants express a mix of agreement and disagreement regarding the understanding of atomic structure and gas behavior. While some points are clarified, there remains uncertainty about the methods of proof and the implications of experimental findings.

Contextual Notes

Participants highlight ambiguities in definitions, such as the term "STP," and the limitations of theoretical reasoning in proving certain principles, emphasizing the reliance on experimental evidence.

scientifico
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Hello, I read that equal volumes of different gas contain the same number of molecules so if I solidify that gases they will occupe different volumes?

How do we know that for example H contain 1 electron 1 proton and 1 neutron, E contain 2 , Li 3, Be 4 and etc..?
is it a consequence of a reasoning or they were counted sperimentally? how?

Thanks!
 
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Yes I believe you are correct. Correct me if I am wrong, but I think a mole or 6.02X10^23 molecules of CO2 gas at STP occupies 22.4 liters. A and a mole or 6.02x10^23 molecules of H2O gas also occupies 22.4liters. As you approach the freezing point of water, the volume decreases until around 4 Celsius, then it expands so as to take the shape of solid ice crystals. Carbon dioxide has a different behavior when it freezes, and since it freezes at a much lower freezing point I am guessing that it might even get a tiny fraction smaller in volume than it would if frozen by high pressure at 0C.
For the second question, I think most H contains 1 electron and 1 proton.
I think most He contains 2 protons and 2 neutrons, most Li contains 3 protons and 4 neutrons. I think we know this from a combination of reasoning with the data from experiments. But I am open to the idea that maybe words could not really describe what really exists. I think that we can use the ideas we have (right or wrong) to make airplanes fly, to make buildings tall, and make Bill Gates wealthy.
 
Last edited:
Fun Value said:
and a mole or 6.02x10^23 molecules of H2O gas also occupies 22.4liters

Water is not a gas at STP, so it doesn't occupy 22.4L. More like 18 mL.

Also note that STP is ambiguous - see http://en.wikipedia.org/wiki/Standard_Temperature_and_Pressure

Number of protons/neutrons in nucleons have been determined experimentally.
 
what experiment was made to know the number of electrons exactly?

thank you
 
Photoelectron spectroscopy has been used to experimentally probe the electron configurations of the elements. I would suspect that the very fleeting heavy elements at the very edge of the known periodic table have probably not been quite as extensively studied as their lighter cousins, of course.
 
Why are we sure that equal volumes of different gases at the same condition (pressure, temperature etc) contain exactly the same number of particles? How is it possible to prove this?
thank you!
 
scientifico said:
Why are we sure that equal volumes of different gases at the same condition (pressure, temperature etc) contain exactly the same number of particles? How is it possible to prove this?

Stoichiometry (for example).
 
scientifico said:
Why are we sure that equal volumes of different gases at the same condition (pressure, temperature etc) contain exactly the same number of particles? How is it possible to prove this?
thank you!

There are no mathematical derivations for it ! The only thing you can do it is logically and theoretically think about it but it will not lead you to its proof. This is because it has been proved experimentally.

Truly said : Chemistry is based on observations.

Even Avogadro's constant is derived experimentally.
6.023 x 1023
 

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