Atoms in a Solid: Why Their Vicinity Matters

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SUMMARY

The discussion centers on the behavior of atoms in solids, emphasizing that atoms occupy a general vicinity due to the principles of Quantum Mechanics, particularly the Uncertainty Principle and wave functions. Atoms in solids are held together by various forces: ionic crystals by electrostatic forces, covalent molecules through valence electron exchange, and metals via the sharing of a "Drude cloud" of free electrons. The significant mass difference between atomic nuclei and electrons contributes to the localization of atoms, while excessive thermal motion can lead to melting, transitioning the material from solid to liquid.

PREREQUISITES
  • Understanding of Quantum Mechanics principles, including the Uncertainty Principle
  • Familiarity with atomic structure and electron behavior
  • Knowledge of solid-state physics concepts, particularly crystal structures
  • Basic comprehension of forces in chemistry, such as ionic and covalent bonding
NEXT STEPS
  • Research the Uncertainty Principle in Quantum Mechanics
  • Explore the concept of wave functions and their implications in atomic behavior
  • Study the properties and structures of ionic and covalent crystals
  • Investigate the Drude model of electrical conduction in metals
USEFUL FOR

Students and professionals in physics, materials science, and chemistry, particularly those interested in solid-state physics and atomic interactions.

obiwan1001
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Why do atoms just have a general vicinity of which they rest in a solid?
 
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A mass of electrons

My theory is that in a solid of like atoms, all of the electrons tend to be shared, forming a giant cloud of electrons that are shared among each other, and with all these negative electrons buzzing around, and positive nuclei, the atoms just kind of hold each other in place.
 
If you look at images from scanning tunneling or atomic force microscopes of solids, you can generally make out a regular crystal pattern. So, the atoms are localized fairly well in a crystal.
 
obiwan1001 said:
Why do atoms just have a general vicinity of which they rest in a solid?

It's a consequence of the fact that, until measured, particles do not have specific locations, and instead have an area of space that they "occupy". I put that in quotations because I want to emphasize that defining the position of a particle is much more complicated than one might think.

Do you know anything about Quantum Mechanics, such as the Uncertainty Principle or what a wave function is?
 
obiwan1001 said:
Why do atoms just have a general vicinity of which they rest in a solid?

Typically it is because they are bound together by some force. For ionic crystals it is an electrostatic force. For covalent molecules it is the exchange of the valence electrons. For metals it is the overall sharing of the "Drude cloud" of free electrons.

Note that the nucleus of any atom is thousands of times heavier than an electron, so their inertia will keep them localized even though they do have some motion. If their motion becomes too great (thermal motion) the material melts, and you no longer have a solid.
 

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