Barium Hydroxide: Use & Benefits for Titrations

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SUMMARY

Barium hydroxide (Ba(OH)2) is preferred over limewater and sodium hydroxide for detecting small quantities of CO2 due to its ability to effectively precipitate carbonate ions as insoluble barium carbonate (BaCO3). This reaction eliminates CO2 by forming a salt and water, making it ideal for titrations where carbonate ions must be excluded. The insolubility of barium carbonate in water further enhances its utility in these applications.

PREREQUISITES
  • Understanding of acid-base reactions
  • Knowledge of precipitation reactions
  • Familiarity with barium compounds and their properties
  • Basic concepts of titration techniques
NEXT STEPS
  • Research the properties and reactions of barium hydroxide (Ba(OH)2)
  • Study the formation and characteristics of barium carbonate (BaCO3)
  • Learn about titration methods that exclude carbonate ions
  • Explore the role of barium compounds in analytical chemistry
USEFUL FOR

Chemistry students, laboratory technicians, and professionals involved in analytical chemistry and titration methods will benefit from this discussion.

meawinner
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I have this question to do for homework and i can't find the answer anywhere so please can someone help me. Barium hydroxide can sometimes be used instead of limewater to detect small quantities of CO2. Why is Barium hydroxide preferred here and in using it instead of sodium hydroxide for titrations where it is important to exclude dissolved carbonate ions? Please help. Thank-you
 
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BaOH reacts with the acidic oxide, the carbon dioxide, to form a salt and water; and thus CO2 is gotten rid of this way. Also barium carbonate is an insoluble substance in water; thus by having barium metals we can effectively precipitate the carbonate.
 
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I think you mean Ba(OH)2?
What does barium carbonate look like?
I looked it up on chemfinder and it shows me the carbonate molecule and the barium ion, which is what it dissociates into I guess. But not in water since it's an insoluble salt, well maybe just a tiny bit but whatever. But the solid form of barium carbonate must have some kind of structure other than the carbonate and barium ions. I guess barium forms a four-sided ring with the two oxygens, or what?
help.
help help...
 
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