Bloch equations for a 3-level system

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SUMMARY

The discussion focuses on the Bloch equations for a three-level quantum system characterized by states |1⟩, |2⟩, and |3⟩, with corresponding energies ℏω₁, ℏω₂, and ℏω₃. The Hamiltonian for the system, derived under the rotating wave approximation, includes off-diagonal elements influenced by two light fields with frequencies ωₚ and ωₕ, coupling states 1 and 3, and states 2 and 3, respectively. The challenge presented involves understanding the off-diagonal elements of the Hamiltonian and the conditions under which the matrix elements vanish, specifically why ⟨1|Hᵢ|2⟩ equals zero.

PREREQUISITES
  • Quantum mechanics fundamentals, particularly the concepts of state vectors and Hamiltonians.
  • Understanding of the rotating wave approximation in quantum systems.
  • Familiarity with Rabi frequencies and dipole interaction Hamiltonians.
  • Knowledge of electric field interactions with quantum states.
NEXT STEPS
  • Study the derivation of the Bloch equations for multi-level systems.
  • Learn about the rotating wave approximation and its implications in quantum mechanics.
  • Explore the mathematical treatment of dipole interactions in quantum optics.
  • Investigate the conditions under which matrix elements vanish in quantum systems.
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Quantum physicists, graduate students in quantum mechanics, and researchers working on multi-level atomic systems or quantum optics applications.

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Homework Statement


"Consider a system with three states, ##|1\rangle , |2\rangle ,|3\rangle ## with energies ##\hbar \omega_1 , \hbar \omega_2 , \hbar \omega_3 ##. the states are then separated by ##\hbar \omega_3 -\hbar \omega_1 = \hbar \omega_{13}## and ## \hbar \omega_3-\hbar \omega_2= \hbar \omega_{23}##. Two separate light fields are incident on the system with frequencies ##\omega_p## and ##\omega_c## respectively, where ##\omega_p## couples states 1 and 3 with a detuning of ##\Delta_p##, and ##\omega_c## couples states 2 and 3 with a detuning of ##\Delta_c##. The loss rates from the excited states ##|2\rangle## and ##|3\rangle## are ##\gamma_2## and ##\gamma_3## respectively.

Show that the H for the system in the rotating wave approx. is ##
\dfrac{\hbar}{2}\begin{pmatrix}
2\omega_{1}& 0 & -\Omega_{p}e^{i\omega_{p}t} \\
0& 2\omega_{2} & -\Omega_{c}e^{i\omega_{c}t}\\
-\Omega_{p}e^{-i\omega_{p}t}& -\Omega_{c}e^{-i\omega_{c}t} & 2\omega_{3}
\end{pmatrix}##

Where the Rabi frequencies ##\Omega_p## and ##\Omega_c## are defined naturally, for example
## \hbar\Omega_{p} = \langle 1 |\vec{d} \cdot \vec{E_{p}}| 3 \rangle ##."

Presumably ##\vec{E_p}## is the vector magnitude of the relevant electric field, i.e. the field coupling state 1 and 3 is described by ##\vec{E_p}\cos (\omega_p t)##.

The Attempt at a Solution


The diagonal elements of the Hamiltonian are straightforward, but we don't understand why the off diagonals look the way they do. In the two-state case, the dipole interaction Hamiltonian is given by ##H_I = -\vec{d}\cdot \vec{E}## where our electric field is ##\vec{E} \cos (\omega t).## Then the off diagonal element is given by ##\langle 1 | H_I | 2 \rangle = \langle 2 | H_I | 1 \rangle ^* = - \langle 1 | \vec{d} \cdot \vec{E} | 2 \rangle \cos (\omega t). ## But in this case we have two electric fields and so ## H_I = -\vec{d} \cdot (\vec{E_p}\cos{w_pt} + \vec{E_c}\cos{w_ct})##. But when we try to take the matrix element of this w.r.t. the different states to find the entries of the Hamiltonian, things aren't working out. For example, why is it that ##\langle 1 | H_I | 2 \rangle = 0 ## ?
 
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