Bloch function - Solid state physics

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SUMMARY

Bloch functions are one-electron wavefunctions utilized in quantum mechanical modeling of crystals, represented by the equation ψ_k(r) = u_k(r)exp(ik·r). These functions can be combined into wave packets to depict electrons moving through the potential fields of ion cores. According to Kittel, the periodic nature of both u_r and e^(ikr) allows for the use of a plane wave basis set to approximate the system's actual wavefunction. This approach enables the calculation of electronic band structures, which are essential for determining various properties of solid materials.

PREREQUISITES
  • Understanding of quantum mechanics principles
  • Familiarity with solid state physics concepts
  • Knowledge of wavefunction representation
  • Basic grasp of electronic band structure analysis
NEXT STEPS
  • Study Bloch's theorem in detail
  • Learn about wave packet formation in quantum mechanics
  • Explore electronic band structure calculations using software tools
  • Investigate the implications of periodic potentials in solid state physics
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Students and researchers in solid state physics, quantum mechanics enthusiasts, and professionals involved in materials science and electronic properties analysis will benefit from this discussion.

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Homework Statement


What are Bloch functions? Explain briefly how these function are used in the quantum mechanical modelling of crystals.

Homework Equations


\psi _k (r)=u_k(r)exp(ik.r)


The Attempt at a Solution


Now I know that a bloch function is a one-electron wavefunction that is given by the above equation. But I don't really know how to explain how it is used for the quantum mechanical modelling of crystals.

Kittel gives this information on a bloch function:
Bloch functions can be assembled into wave packets to represent electrons that propagate freely trhough the potential field of the ion cores.

To me this description answers it and hell the equation gives the relationship between the electron wavefunction with the periodicity of the crystal lattice so I would have thought that, that is quantum mechanic modelling in itself. Is there something else I should be putting down or have I just interpreted this incorrectly.

Any help is greatly appreciated.
 
Physics news on Phys.org
##u_r## and ##e^{ikr}## are both periodic by Bloch’s theorem, so we can use a plane wave basis set to approximate the actual wavefunction of the system. By calculating at a number of crystal moments, we can work out the electronic band structure of the material, which we can use to get a long list of properties of the solid.
 

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