Bound states in finite spherical well

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SUMMARY

The discussion focuses on finding bound states in a finite spherical potential well, specifically for the case of a radial equation with angular momentum quantum number l = 0. The differential equations derived are solved for regions inside and outside the well, leading to the conditions for continuity at the boundary. The key equation for determining bound states is established as \(\frac{1}{k} \tan(ka) = -\frac{1}{\kappa}\), where \(k\) and \(\kappa\) are defined in terms of the potential depth \(V_0\) and energy \(E\). The participants emphasize the importance of understanding the relationship between bound states (E < 0) and the transcendental equation involving \(\tan(ka)\).

PREREQUISITES
  • Understanding of quantum mechanics, particularly the Schrödinger equation.
  • Familiarity with spherical coordinates and radial equations.
  • Knowledge of boundary conditions and continuity in wave functions.
  • Concept of bound states and their energy characteristics.
NEXT STEPS
  • Study the derivation of the radial Schrödinger equation in spherical coordinates.
  • Learn about the properties of transcendental equations and their solutions.
  • Explore the concept of potential wells and their implications in quantum mechanics.
  • Review the chapter on one-dimensional finite wells for additional context on bound states.
USEFUL FOR

Students and professionals in quantum mechanics, particularly those studying potential wells, wave functions, and bound state solutions. This discussion is beneficial for anyone seeking to deepen their understanding of quantum systems and their mathematical foundations.

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Homework Statement


upload_2015-5-13_21-11-58.png


Homework Equations

The Attempt at a Solution


for ##r \le a## and ##l = 0##, the radial equation is

$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - V_{0} = Eu $$
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - [V_{0} + E]u = 0$$
call ##k^{2} = \frac {2m}{\hbar^{2}}[V_{0} + E]##
The solution to this differential equation comes out to be
$$u(r) = A sin(kr) + B cos(kr)$$
Since ##u = R(r)r##, as ##r \rightarrow 0##, then ##\frac {cos(kr)}{r} \rightarrow \infty##, therefore ##B = 0##
Leaving ##u(r) = Asin(kr)##

For ##r > a##
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} = Eu$$
##\kappa^{2} = - \frac {2mE}{\hbar^{2}}##
therefore, ##u(r) = Ce^{-\kappa r} + De^{\kappa r}##
As ##r \rightarrow \infty##, then the second term blows up, so ##D = 0##

At the ##r = a##, the ##u(r)## must be the same for both sides. Therefore,
##A sin(ka) = Ce^{- \kappa a}##
Also, the function must be continuous, so the derivative must be equal at ##r = a##
## kA cos(ka) = - \kappa C e^{-\kappa a}##
Dividing through,
$$\frac {1}{k} tan(ka) = - \frac {1}{\kappa}$$

From here, how am I supposed to find the bound states? I have always been confused about bound and unbound states.
 
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Hi Maylis,
Try to expand tan(ka)
Note that the ground state have E~0
but no zero, we can give it a great approximation !
 
Maylis said:

Homework Statement


View attachment 83427

Homework Equations

The Attempt at a Solution


for ##r \le a## and ##l = 0##, the radial equation is

$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - V_{0} = Eu $$
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - [V_{0} + E]u = 0$$
call ##k^{2} = \frac {2m}{\hbar^{2}}[V_{0} + E]##
The solution to this differential equation comes out to be
$$u(r) = A sin(kr) + B cos(kr)$$
Since ##u = R(r)r##, as ##r \rightarrow 0##, then ##\frac {cos(kr)}{r} \rightarrow \infty##, therefore ##B = 0##
Leaving ##u(r) = Asin(kr)##

For ##r > a##
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} = Eu$$
##\kappa^{2} = - \frac {2mE}{\hbar^{2}}##
therefore, ##u(r) = Ce^{-\kappa r} + De^{\kappa r}##
As ##r \rightarrow \infty##, then the second term blows up, so ##D = 0##

At the ##r = a##, the ##u(r)## must be the same for both sides. Therefore,
##A sin(ka) = Ce^{- \kappa a}##
Also, the function must be continuous, so the derivative must be equal at ##r = a##
## kA cos(ka) = - \kappa C e^{-\kappa a}##
Dividing through,
$$\frac {1}{k} tan(ka) = - \frac {1}{\kappa}$$

From here, how am I supposed to find the bound states? I have always been confused about bound and unbound states.

Bound states are defined by E < 0, which you assumed to get the solution outside the well. So, this is the solution for bound states you have.

To solve the transcendental equation in ##tan(ka)## you need a bit of jiggery-pokery. See the earlier chapter on the 1D finite well for how it's done. Let ##z = ka## etc.
 

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