Bound states in finite spherical well

In summary, the conversation discusses the solution to the radial equation for a particle in a 1D infinite potential well. The solution for ##r \le a## and ##l = 0## is given by ##u(r) = Asin(kr)##, and for ##r > a##, it is ##u(r) = Ce^{-\kappa r}##. The condition for finding bound states is that the energy, E, must be less than 0. To solve the transcendental equation for bound states, one can use the method shown in an earlier chapter on the 1D finite well.
  • #1
gfd43tg
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Homework Statement


upload_2015-5-13_21-11-58.png


Homework Equations

The Attempt at a Solution


for ##r \le a## and ##l = 0##, the radial equation is

$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - V_{0} = Eu $$
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - [V_{0} + E]u = 0$$
call ##k^{2} = \frac {2m}{\hbar^{2}}[V_{0} + E]##
The solution to this differential equation comes out to be
$$u(r) = A sin(kr) + B cos(kr)$$
Since ##u = R(r)r##, as ##r \rightarrow 0##, then ##\frac {cos(kr)}{r} \rightarrow \infty##, therefore ##B = 0##
Leaving ##u(r) = Asin(kr)##

For ##r > a##
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} = Eu$$
##\kappa^{2} = - \frac {2mE}{\hbar^{2}}##
therefore, ##u(r) = Ce^{-\kappa r} + De^{\kappa r}##
As ##r \rightarrow \infty##, then the second term blows up, so ##D = 0##

At the ##r = a##, the ##u(r)## must be the same for both sides. Therefore,
##A sin(ka) = Ce^{- \kappa a}##
Also, the function must be continuous, so the derivative must be equal at ##r = a##
## kA cos(ka) = - \kappa C e^{-\kappa a}##
Dividing through,
$$\frac {1}{k} tan(ka) = - \frac {1}{\kappa}$$

From here, how am I supposed to find the bound states? I have always been confused about bound and unbound states.
 
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  • #2
Hi Maylis,
Try to expand tan(ka)
Note that the ground state have E~0
but no zero, we can give it a great approximation !
 
  • #3
Maylis said:

Homework Statement


View attachment 83427

Homework Equations

The Attempt at a Solution


for ##r \le a## and ##l = 0##, the radial equation is

$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - V_{0} = Eu $$
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} - [V_{0} + E]u = 0$$
call ##k^{2} = \frac {2m}{\hbar^{2}}[V_{0} + E]##
The solution to this differential equation comes out to be
$$u(r) = A sin(kr) + B cos(kr)$$
Since ##u = R(r)r##, as ##r \rightarrow 0##, then ##\frac {cos(kr)}{r} \rightarrow \infty##, therefore ##B = 0##
Leaving ##u(r) = Asin(kr)##

For ##r > a##
$$- \frac {\hbar^{2}}{2m} \frac {d^{2}u}{dr^{2}} = Eu$$
##\kappa^{2} = - \frac {2mE}{\hbar^{2}}##
therefore, ##u(r) = Ce^{-\kappa r} + De^{\kappa r}##
As ##r \rightarrow \infty##, then the second term blows up, so ##D = 0##

At the ##r = a##, the ##u(r)## must be the same for both sides. Therefore,
##A sin(ka) = Ce^{- \kappa a}##
Also, the function must be continuous, so the derivative must be equal at ##r = a##
## kA cos(ka) = - \kappa C e^{-\kappa a}##
Dividing through,
$$\frac {1}{k} tan(ka) = - \frac {1}{\kappa}$$

From here, how am I supposed to find the bound states? I have always been confused about bound and unbound states.

Bound states are defined by E < 0, which you assumed to get the solution outside the well. So, this is the solution for bound states you have.

To solve the transcendental equation in ##tan(ka)## you need a bit of jiggery-pokery. See the earlier chapter on the 1D finite well for how it's done. Let ##z = ka## etc.
 

1. What are bound states in a finite spherical well?

Bound states in a finite spherical well refer to the quantum mechanical states of a particle confined within a finite space, such as a spherical potential well. These states have discrete energy levels and the particle is unable to escape from the well due to the potential barrier.

2. How are bound states in a finite spherical well different from bound states in an infinite well?

Bound states in a finite spherical well are different from bound states in an infinite well in terms of the potential barrier and the shape of the well. In an infinite well, the potential barrier is infinitely high, whereas in a finite spherical well, the potential barrier is finite and the shape of the well is spherical instead of rectangular.

3. What factors affect the number of bound states in a finite spherical well?

The number of bound states in a finite spherical well is affected by the depth and width of the well, as well as the mass and energy of the particle. A deeper and narrower well will have fewer bound states, while a shallower and wider well will have more bound states. A heavier particle will also have fewer bound states compared to a lighter particle.

4. How do bound states in a finite spherical well relate to the Schrödinger equation?

The Schrödinger equation is used to describe the behavior of quantum particles, including those in a finite spherical well. The solutions to the Schrödinger equation for a finite spherical well give the allowed energy levels and wavefunctions of the bound states in the well.

5. What applications do bound states in a finite spherical well have in science and technology?

Bound states in a finite spherical well have various applications in physics, such as in understanding the properties of atoms and molecules, as well as in the development of semiconductor devices. They also have applications in nuclear physics, such as in the study of nuclear structure and nuclear reactions.

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