Bragg condition reflection vs. diffraction

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Discussion Overview

The discussion revolves around the Bragg condition for constructive interference of waves in crystals, specifically addressing the relationship between reflection and diffraction of x-rays. Participants explore the theoretical underpinnings of the Bragg condition and its applicability despite the diffraction nature of x-ray interactions with crystal lattices.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant questions why the Bragg condition, which is based on reflection, is applicable to x-ray diffraction, suggesting that there should always be a ray that refracts to produce constructive interference.
  • Another participant notes that Bragg's approach simplifies the more complex Laue refraction equation, indicating that Bragg's assumption of treating diffraction as reflection led to a more straightforward condition.
  • A participant expresses confusion about the validity of the Bragg condition, questioning the reasoning behind its effectiveness despite being based on what they describe as an "unphysical" assumption of reflection.
  • In response, a participant clarifies that the scattering of x-rays can indeed be viewed as reflections from crystal planes, and at specific angles, these reflections can constructively interfere, allowing for the use of Bragg's equation to calculate interplanar spacing.

Areas of Agreement / Disagreement

Participants express differing views on the validity of the reflection model in the context of x-ray diffraction. While some acknowledge the utility of the Bragg condition, others challenge its foundational assumptions, leading to an unresolved debate regarding the nature of the underlying physics.

Contextual Notes

Participants reference the Laue equations and the complexities of diffraction, indicating that the discussion may depend on specific definitions and interpretations of reflection versus diffraction. The relationship between these concepts remains a point of contention.

frater
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I've been asking myself this question that is not entirely clear to me: the Bragg condition used to describe the constructive interference of waves on a crystal is based on the assumption of reflection. However, x-rays diffract on a crystal rather than reflect, so theoretically there is always some ray which refracts at an angle that would yield a path difference just right to produce constructive interference. Why then does the Bragg condition based on a reflection model work?

Thanks for any answers!
 
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You are right...but that takes you back to Laue refraction equation, a few months before Bragg's equation and its more complicated.
It was Bragg's assumption to treat diffraction as reflection from lattice planes which led him to the simpler well known condition.
 
Well ok, I understand that the full description the underlying physics is given by the Laue equations. But what I don't understand is why does the Bragg condition work at all since it is based on an "unphysical" assumption of reflection. Is there some simple reasoning I am missing why the reflection description, even if not correct, nevertheless accurately produces the condition for constructive diffraction?
 
"it is based on an "unphysical" assumption of reflection"

Not like that...There is real reflection, in the sense that the combined scattering of x-rays from crystal planes can be looked upon as reflections from these planes.

At certain glancing angles, these reflections are in phase and produce maximum intensity. By measuring theses angles for different set of planes, knowing the wavelength, we can calculate interplanar spacing from Bragg's eq.
 

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