Brown Ring Test for NO3-: FeSO4 + H2SO4?

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SUMMARY

The brown ring test for nitrate ions (NO3-) involves the reaction of freshly prepared ferrous sulfate (FeSO4) with concentrated sulfuric acid (H2SO4). The correct procedure is to first mix NO3- with FeSO4 and then carefully add H2SO4 to the mixture. This method ensures that FeSO4 is positioned at the bottom of the test tube, allowing for the formation of a distinct brown ring at the interface of the liquid layers. The brown ring is attributed to the formation of the complex ion [Fe(H2O)5NO]2+, which is crucial for the test's success.

PREREQUISITES
  • Understanding of chemical reactions and ionic compounds
  • Familiarity with the properties of ferrous sulfate (FeSO4)
  • Knowledge of concentrated sulfuric acid (H2SO4) handling and safety
  • Basic laboratory techniques for conducting chemical tests
NEXT STEPS
  • Research the mechanism of the brown ring test for nitrate detection
  • Learn about the preparation and properties of ferrous sulfate (FeSO4)
  • Study the effects of concentrated sulfuric acid (H2SO4) in chemical reactions
  • Explore other qualitative tests for detecting anions in solution
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Chemistry students, laboratory technicians, and educators involved in analytical chemistry and qualitative analysis of nitrate ions.

campa
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when considering the brown ring test to test NO3- do you first have to mix NO3- and H2SO4 together and then put newly made FeSO4 or
first mix NO3- and newly made FeSO4 together and then pour H2SO4
or does it it make any difference either way
 
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FeSO4 is to be out in the end along the sides of the test tube leading to the formation of a brown ring along the circumfrence of the liquid layer.
 
Is there a reason for this?
 

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