Built-in voltage of pn junction diode

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Discussion Overview

The discussion revolves around the built-in voltage of a pn junction diode and why it cannot be measured with a voltmeter when the diode is isolated. Participants explore the nature of this voltage, the role of current flow, and the concept of contact potentials at the junctions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants assert that the built-in voltage exists only when current flows, suggesting that a voltmeter does not cause significant current flow to measure it.
  • There is a question raised about why the diode does not act like a voltage source, with references to the presence of positive and negative charges, likening it to an electric dipole.
  • One participant mentions that the contact potentials at the p-metal and n-metal junctions counteract the built-in potential, which is presented as a more precise explanation.
  • Another participant seeks clarification on the concept of contact potential and its relation to the built-in voltage.
  • A reference to Schottky diodes is made, highlighting the junction between metal and semiconductor and how diffusion voltages at these junctions compensate for the internal pn junction's diffusion voltage.
  • A participant notes that this topic has been discussed in previous threads, suggesting that it is a common question within the community.

Areas of Agreement / Disagreement

Participants express varying viewpoints on the nature of the built-in voltage and its measurement, with no consensus reached on the explanations provided. The discussion remains unresolved regarding the nuances of contact potentials and their implications.

Contextual Notes

There are limitations in understanding the relationship between built-in voltage, current flow, and contact potentials, as well as the definitions of terms used in the discussion. Some assumptions about the behavior of the diode in isolation are not fully explored.

cnh1995
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Why can't the built-in voltage of diode be measured by a voltmeter when the diode is isolated? A potential difference of almost 0.7V exists at the junction, which is clearly not too small for the voltmeter to detect. What's the reason?
 
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Because the voltage is there only when a current flows. The voltmeter won't cause a significant current flow.

It is not a voltage source like a battery.
 
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anorlunda said:
Because the voltage is there only when a current flows. The voltmeter won't cause a significant current flow.
Why does it not act like a voltage source? There are +ve and -ve charges present. Isn't it like an electric dipole?
 
A more precise answer is because the contact potentials at the p-metal and n-metal junctions exactly counteract the built-in potential.
 
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marcusl said:
A more precise answer is because the contact potentials at the p-metal and n-metal junctions exactly counteract the built-in potential.
That's what I read somewhere but didn't understand fully. Could you please elaborate? What exactly is the contact potential?
 
cnh1995 said:
That's what I read somewhere and didn't understand fully. Could you please elaborate?
Did you hear already about a Schottky diode? This a junction between metal and semiconductor - and exactly such a junction exists (necessarily) caused by the contact material at both ends of the pn diode. And the diffusion voltages at these junctions compensate the diffusion voltage across the internal pn junction.
 
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This is a common question and has been the subject of a number of threads at Physics Forums such as
https://www.physicsforums.com/threads/pn-junction-open-conditions-conservation-of-energy.478671/
A simple graphical explanation showing why this must be true is on the first two pages here:
https://www.google.com/url?sa=t&rct...rd0cCNe0g6l2U98TPl1EMg&bvm=bv.107467506,d.cGc
The important point is that the metal part of the circuit is all at the same (0) potential, so Vbi must appear in reverse at each semiconductor contact.
 
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