Calcium Hydride vs Dihydride: Explained

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SUMMARY

Calcium hydride, denoted as CaH2, is correctly named without the prefix "di-" because it is an ionic compound. In ionic compounds, the use of prefixes like mono-, di-, or tri- is unnecessary due to the specific charges of ions, which clarify the ratio of cations to anions. Both "calcium hydride" and "calcium dihydride" are technically correct, but the former is the preferred nomenclature in accordance with IUPAC guidelines.

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jools111
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Hey all. I'm pretty sure I'd be correct in saying that the compund CaH2 is calcium hydride. My question is this... Why would it not be calcium dihydride? There are 2 hydrogen atoms right? Or are both term correct? Thanks.
 
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Nothing wrong with "dihydride". I am not sure, but could be this is even IUPAC recommended name. Check here:

http://www.iupac.org/publications/books/rbook/Red_Book_2005.pdf

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Generally for ionic substances (usually substances formed between a metal and non-metal), you don't need to use the mono-, di-, tri- etc. prefixes to specify number. This is because most ions have a specific charge (or for transition metals, the charge is specified), so one can figure out the correct proportion of cations and anions.
 
Ygggdrasil said:
Generally for ionic substances (usually substances formed between a metal and non-metal), you don't need to use the mono-, di-, tri- etc. prefixes to specify number. This is because most ions have a specific charge (or for transition metals, the charge is specified), so one can figure out the correct proportion of cations and anions.

So technically... Calcium hydride or calcium dihydride would both be correct?
 
Yes.

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