Calcium Hydride vs Dihydride: Explained

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Discussion Overview

The discussion centers around the nomenclature of the compound CaH2, specifically whether it should be referred to as calcium hydride or calcium dihydride. The scope includes conceptual clarification regarding chemical naming conventions and the implications of ionic compound nomenclature.

Discussion Character

  • Conceptual clarification, Debate/contested

Main Points Raised

  • One participant asserts that CaH2 is calcium hydride and questions the use of the term calcium dihydride, noting the presence of two hydrogen atoms.
  • Another participant suggests that "dihydride" is also acceptable and speculates that it may be the IUPAC recommended name, referencing an external source.
  • A third participant explains that for ionic compounds, prefixes like mono- and di- are typically unnecessary because the charges of ions provide clarity on the proportions of cations and anions.
  • This participant reiterates that both terms, calcium hydride and calcium dihydride, could be considered correct.
  • A later reply confirms the correctness of the previous assertion regarding the acceptability of both terms.

Areas of Agreement / Disagreement

Participants generally agree that both "calcium hydride" and "calcium dihydride" are acceptable terms, but there is some debate about the necessity of using prefixes in the context of ionic compounds.

Contextual Notes

The discussion does not resolve whether one term is preferred over the other in formal contexts, nor does it clarify the implications of IUPAC naming conventions fully.

jools111
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Hey all. I'm pretty sure I'd be correct in saying that the compund CaH2 is calcium hydride. My question is this... Why would it not be calcium dihydride? There are 2 hydrogen atoms right? Or are both term correct? Thanks.
 
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Nothing wrong with "dihydride". I am not sure, but could be this is even IUPAC recommended name. Check here:

http://www.iupac.org/publications/books/rbook/Red_Book_2005.pdf

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Last edited by a moderator:
Generally for ionic substances (usually substances formed between a metal and non-metal), you don't need to use the mono-, di-, tri- etc. prefixes to specify number. This is because most ions have a specific charge (or for transition metals, the charge is specified), so one can figure out the correct proportion of cations and anions.
 
Ygggdrasil said:
Generally for ionic substances (usually substances formed between a metal and non-metal), you don't need to use the mono-, di-, tri- etc. prefixes to specify number. This is because most ions have a specific charge (or for transition metals, the charge is specified), so one can figure out the correct proportion of cations and anions.

So technically... Calcium hydride or calcium dihydride would both be correct?
 
Yes.

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