Calculate the Electron Affinity of F(g) in kJ/mole using Hess' Law?

In summary, to calculate the Electron Affinity of F(g) in kJ/mole using Hess' Law, we can use the following equations: 1. Sr(g)+Sr+(g) -> Sr2+(g) + Sr+(g) + 2e-2. Sr (s) -> Sr(g)3. F2(g) -> 2F(g)4. Sr(s) + F2(g) -> SrF25. 2Sr2+(g) + 2F-(g) -> 2SrF2 (s)We can then flip equation 5 and use the properties of Hess' Law to calculate the electron affinity. However, we must also note that in equation
  • #1
greenglasses
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Homework Statement


Calculate the Electron Affinity of F(g) in kJ/mole using Hess' Law.
IE1 + IE2 of Sr(g) is 1580 kj
Hsub of Sr(s) is 144 kJ
Hdiss of F2 is 79 kJ
Hf of SrF2 (s) is -1215 kJ
Hlatt of SrF2 (s) is -2441 kJ

Homework Equations



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The Attempt at a Solution


1. Sr(g)+Sr+(g) -> Sr2+(g) + Sr+(g) + 2e-
2. Sr (s) -> Sr(g)
3. F2(g) -> 2F(g)
4. Sr(s) + F2(g) -> SrF2
5. Sr2+(g) + F-(g) -> SrF2 (s)

I tried to:

flip 5
1/2 * flip 3
flip 1
flip 2
copy 4

but when I did that, I ended up with an extra 1/2 F2 that I couldn't cancel out. I'm not sure what to do.
 
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  • #2
In 5. there is a 2 missing before F-
 

1. What is Hess' Law and how is it used to calculate electron affinity?

Hess' Law is a thermodynamic principle that states the total energy change in a chemical reaction is independent of the pathway taken. This means that the initial and final states of a reaction are the same regardless of the steps taken to get there. To calculate the electron affinity of F(g) using Hess' Law, we can use a series of reactions with known electron affinities to determine the overall energy change for the desired reaction.

2. What is electron affinity and why is it important?

Electron affinity is the amount of energy released when an electron is added to an atom or molecule. It is important because it can help us understand the reactivity and stability of elements and compounds. A high electron affinity indicates that an element or compound is more likely to gain electrons and form anions, while a low electron affinity suggests a lower tendency to gain electrons.

3. How do we determine the electron affinity of F(g) using Hess' Law?

To determine the electron affinity of F(g), we can use a series of reactions where F(g) is a product or reactant and the electron affinity is known. By adding the reactions together and canceling out common species, we can calculate the overall energy change for the desired reaction. This value will be equal to the electron affinity of F(g).

4. Are there any limitations to using Hess' Law to calculate electron affinity?

Yes, there are some limitations to using Hess' Law. It assumes that the reactions involved are thermodynamically feasible, meaning they can occur under standard conditions. Additionally, this method only gives an estimate of the electron affinity since it is based on a series of reactions rather than direct measurement.

5. What unit is used to express electron affinity and how is it typically reported?

Electron affinity is typically reported in units of kilojoules per mole (kJ/mol). This unit represents the amount of energy released when one mole of electrons is added to a mole of atoms or molecules. It is also common for electron affinity to be reported as a negative value, indicating the release of energy during the process.

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