A total station is a theodolite with a laser rangefinder, since it can measure 2 angles (the theodolite part) and distance (the laser) you can measure the relative position of anything you can see with high accuracy (mm).
RTK-GPS is a special type of GPS receiver that can measure the relative position between a pair of them to high accuracy (a few mm).
See wikipedia for details - or a survey supplies company.
As I said it depends wether this is a homework or an engineering question.