Calculating Collision Frequency of Electrons in Copper Cube

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SUMMARY

The discussion focuses on calculating the collision frequency of conduction electrons in a 1.00-cm cube of copper, confirming the claim that electrons collide with the surface at a rate of approximately 1030 per second per square centimeter. The number of conduction electrons is determined to be 8.48 x 1023 electrons/cm3, based on copper's density of 8.95 g/cm3. The speed of each electron is calculated using the kinetic energy of 7.00 eV, yielding a velocity of 1.57 x 106 m/s. The discussion also suggests methods for estimating the time it takes for an electron to travel across the cube and return, indicating a refined approach using statistical mechanics.

PREREQUISITES
  • Copper density of 8.95 g/cm3
  • Kinetic energy calculations using electron volts (eV)
  • Basic principles of statistical mechanics
  • Understanding of Fermi-Dirac statistics
NEXT STEPS
  • Learn about the Fermi Dirac gas model and its applications in solid-state physics
  • Study the partition function and its role in statistical mechanics
  • Explore the derivation of collision frequency in metals
  • Investigate the implications of electron mobility in conductive materials
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Physics students, materials scientists, and electrical engineers interested in the behavior of conduction electrons in metals and their collision dynamics.

hnnhcmmngs
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Homework Statement
Verify the claim of Section 7.2 that the electrons of a metal collide with the surface at a rate of about 10^30 per second per square centimeter. Do this by estimating the collision frequency of electrons in a 1.00-cm cube of copper metal with one face of the cube surface. Assume that each copper atom contributes one conduction electron to the metal (the chemical valence of copper is 􏰄1) and that these conduction electrons move freely with kinetic energy equal to 7.00 eV.
Relevant Equations
I don't know which equations are relevant for this question.
Homework Statement: Verify the claim of Section 7.2 that the electrons of a metal collide with the surface at a rate of about 10^30 per second per square centimeter. Do this by estimating the collision frequency of electrons in a 1.00-cm cube of copper metal with one face of the cube surface. Assume that each copper atom contributes one conduction electron to the metal (the chemical valence of copper is 􏰄1) and that these conduction electrons move freely with kinetic energy equal to 7.00 eV.
Homework Equations: I don't know which equations are relevant for this question.

First, I just determined the number of electrons per cm^3 knowing the density of copper is 8.95 g.cm^3.
n = 6.02 * 10^23 atoms/mol * 8.95 g/cm^3 * 1 mol/63.5 g = 8.48 * 10^23 electrons/cm^3
I also determined the speed of each electron.
v = sqrt(2E/M) = 1.57 * 10^6 m/s
I just don't know how to proceed from here. Any help would be appreciated!
 
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hnnhcmmngs said:
Homework Statement: Verify the claim of Section 7.2 that the electrons of a metal collide with the surface at a rate of about 10^30 per second per square centimeter. Do this by estimating the collision frequency of electrons in a 1.00-cm cube of copper metal with one face of the cube surface. Assume that each copper atom contributes one conduction electron to the metal (the chemical valence of copper is 􏰄1) and that these conduction electrons move freely with kinetic energy equal to 7.00 eV.
Homework Equations: I don't know which equations are relevant for this question.

Homework Statement: Verify the claim of Section 7.2 that the electrons of a metal collide with the surface at a rate of about 10^30 per second per square centimeter. Do this by estimating the collision frequency of electrons in a 1.00-cm cube of copper metal with one face of the cube surface. Assume that each copper atom contributes one conduction electron to the metal (the chemical valence of copper is 􏰄1) and that these conduction electrons move freely with kinetic energy equal to 7.00 eV.
Homework Equations: I don't know which equations are relevant for this question.

First, I just determined the number of electrons per cm^3 knowing the density of copper is 8.95 g.cm^3.
n = 6.02 * 10^23 atoms/mol * 8.95 g/cm^3 * 1 mol/63.5 g = 8.48 * 10^23 electrons/cm^3
I think you might be off by 1 order of magnitude there. You might want to double check your exponents.
I also determined the speed of each electron.
v = sqrt(2E/M) = 1.57 * 10^6 m/s
I just don't know how to proceed from here. Any help would be appreciated!

Given your velocity calculation, how long would it take for a single electron to travel in a cube of 1 cm length, from one side to the other, if it just moves freely?

Or better yet, since you're only supposed to consider a single side, how long would it take for the round trip: where it starts at one side, bounces off the opposite side, and then returns to the original side?
 
Well the answer varies as it depends on what "level" you have reached. A crude treatment gives answer as $1/6×n×v$ which on refining gives $1/4×n×v$. If you treat electron as Fermi Dirac gas,then the answer is to evaluate partition function and use partition function(See Reif, Fundamentals of Statistical And Thermal Physics)
 

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