Calculating Expectation Value for E in Wavefunction

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SUMMARY

The discussion centers on calculating the expectation value for the wavefunction defined as sqrt(2/L) sin(2pix / L). The participant initially applies the shortcut method, leveraging the property of eigenvalues in quantum mechanics, but seeks to verify the result through direct integration of the Hamiltonian. Upon integration, they obtain a value of 2 h^2 / mL^2, which does not match the expected energy value E_2 = h^2 / 2mL^2 derived from the 1D Schrödinger equation. The discrepancy suggests a potential error in the integration process.

PREREQUISITES
  • Understanding of quantum mechanics principles, specifically wavefunctions and eigenvalues.
  • Familiarity with the 1D Schrödinger equation and its solutions.
  • Knowledge of Hamiltonian operators in quantum mechanics.
  • Proficiency in performing integrals involving complex conjugates of wavefunctions.
NEXT STEPS
  • Review the derivation of the 1D Schrödinger equation and its eigenvalues.
  • Learn about Hamiltonian operators and their application in quantum mechanics.
  • Practice integrating wavefunctions, focusing on the use of complex conjugates.
  • Explore normalization conditions for quantum wavefunctions to ensure accurate calculations.
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Students and professionals in physics, particularly those studying quantum mechanics, as well as anyone involved in calculations related to wavefunctions and expectation values in quantum systems.

jaejoon89
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I'm trying to check that the expectation value <E> is E for the wavefunction

sqrt(2/L) sin(2pix / L)

I know the shortcut way of doing it by saying that the hamiltonian multiplied by the function is just the eigenvalue E multiplied by the function, and since the function is normalized the answer is E. However, I want to try to check it:

But when I take the hamiltonian of the function (V=0) and then multiply that by the complex conjugate and integrate from 0 to L I get

2 h^2 / mL^2

which is not quite what I would expect if it equals E since I know for the 1D Schrödinger equation

E_n = n^2 h^2 / 8mL^2
=>E_2 = h^2 / 2mL^2

What's wrong?
 
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You must be integrating incorrectly, if you show your calculations, we can point out your error...
 

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