Calculating Lowest Energy Levels of a Rigid Spherical/Cubic Box

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Homework Help Overview

The problem involves determining the lowest energy levels, degeneracies, and quantum numbers for an electron in both a rigid spherical box and a rigid cubic box, with a specific focus on expressing results in terms of given physical constants and units.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the application of Schrödinger's equation in spherical coordinates and the appropriate ansatz for solving 3D problems. There is uncertainty expressed regarding how to approach three-dimensional quantum mechanics.

Discussion Status

Some participants have offered guidance on starting points for the problem, including the formulation of Schrödinger's equation. There is an ongoing exploration of the necessary mathematical tools and concepts needed to tackle the problem.

Contextual Notes

Participants are navigating the complexities of 3D quantum mechanics and are considering how to effectively communicate mathematical expressions within the forum's constraints.

quantumdude10
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Homework Statement



Determine the four lowest energy levels, their degeneracies and quantum numbers of the wavefunctions for an electron in

i) a rigid spherical box of 2 Angstrom radius and,

ii) a rigid cubic box of the same volume

Express the result in multiples of ħ2/(2m0a2), and in electron Volt units. Plot the result on energy level diagrams and comment.


Homework Equations


Schroedinger's equation in spherical coordinates...


The Attempt at a Solution



Not sure how to solve 3d questions...
 
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Welcome to Physics Forums.

How about we start with writing out Schrödinger's equation with the laplacian in spherical coordinates.

Do you know what the usual ansatz is for 3D spherically symmetric problems?
 
you mean this one?

is there a way to post those equations to the body directly and not as an attachment?
 

Attachments

  • SchroedingerSpherical.gif
    SchroedingerSpherical.gif
    3.8 KB · Views: 539
quantumdude10 said:
you mean this one?
That's the one. Now, do you know the appropriate ansatz?
 

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