Calculating Molar Enthalpy of C2H4 Combustion w/ Hess's Law

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Discussion Overview

The discussion revolves around calculating the molar enthalpy of reaction for the combustion of ethene (C2H4) using Hess's Law. Participants explore the necessary steps and components involved in the calculation, including the formation enthalpies of reactants and products.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant expresses confusion about how to balance the reaction and the role of oxygen in the equation, questioning whether to multiply it by 3.
  • Another participant suggests including the formation enthalpy of ethylene in the calculation to arrive at the correct answer.
  • A different participant advises starting from the elemental forms of the compounds to construct the enthalpy changes.
  • A later reply corrects an earlier equation presented by a participant, indicating that the calculation should include the formation enthalpy of ethylene.

Areas of Agreement / Disagreement

Participants do not appear to reach a consensus on the correct approach to the calculation, as there are differing opinions on the necessary components and steps involved.

Contextual Notes

Some participants mention specific enthalpy values and the need to consider formation enthalpies, but there are unresolved questions about the correct balancing of the reaction and the inclusion of certain terms in the calculation.

Who May Find This Useful

This discussion may be useful for students studying thermodynamics, particularly those learning about Hess's Law and enthalpy calculations in chemical reactions.

XxphysicsxX
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Homework Statement


Using Hess's Law and any necessary information from your Data Booklet, calculate the molar enthalpy of reaction for the combustion of ethene in kJ/mol.

im so lost!
i was going to find each sections molar en thalpy and then balance it but what's oxygens and do i multiply it by 3?


The Attempt at a Solution


C2H4 + 3 O2 --------------- 2CO2 + 2H2O

(+52.4)----->[2 x -393.5) + (2 x -285.8)] -[ 3 x 0)]


shouldnt there be three formulas basically?
so:
formation of 3O2 ------->
formation of 2H2O------>
formation of 2CO2------->

and then their enthalpy change?

then i balance all three and get the answer to


C2H4 + 3O2 ---> 2CO2 + 2H2O
?

can someone help with the three fomulas please?
thankyou!
 
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Just make sure the formation enthalpy of ethylene is in there too and you should get the right answer.
 
Start from the elements making the compounds.
 
XxphysicsxX said:

Homework Statement


Using Hess's Law and any necessary information from your Data Booklet, calculate the molar enthalpy of reaction for the combustion of ethene in kJ/mol.

im so lost!
i was going to find each sections molar en thalpy and then balance it but what's oxygens and do i multiply it by 3?

The Attempt at a Solution


C2H4 + 3 O2 --------------- 2CO2 + 2H2O

(+52.4)----->[2 x -393.5) + (2 x -285.8)] -[ 3 x 0)]
This equation is incorrect. It should be

##\Delta H## =[2 x -393.5) + (2 x -285.8)] -[ 3 x 0)]-[1 x 52.4]
 

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