• Support PF! Buy your school textbooks, materials and every day products Here!

Calculating pH from deltaG° and Ion Concentrations

  • Thread starter RNix25
  • Start date
  • #1
2
0
I've been working on this one for a few days, and I just cant seem to get the right answer.

Consider the reaction I2(s) --> I- (aq) + IO3- (aq)
Balanced= 3I2 + 6OH- --> 5I- + IO3- + 3H2O

deltaG°= -153.8 kJ/mol

The question: What pH is required for the reaction to be at equilibrium at 298 K when [I-]= 0.5 M and [IO3-]= 0.5 M

I know the answer is 9.21, but I just can't figure out how to get there. I started by finding Keq, which is 9.113 * 10^26, but I'm stumped from there. I would be extremely appreciative for a walkthrough to the final answer.
 

Answers and Replies

  • #2
uby
176
0
Sounds like this should go in the homework help section.

Your K value looks correct. Write out K in terms of the concentrations of species raised to the power of their stoichiometric coefficients and solve for [OH-]. pH = 14 + log[OH-], I get 9.206 using your values.
 
  • #3
2
0
I slept on it and when I woke up, I looked over it and figured out where I was going wrong. Had one of my concentrations wrong, so I kept getting the wrong value when I worked it. I already had the answer, I just couldn't figure out why my math wasn't producing it. Anyway, your method was exactly right, so thanks for the help.

Don't know protocol on these boards, but if it is proper, a mod can close/delete this thread.
 

Related Threads for: Calculating pH from deltaG° and Ion Concentrations

  • Last Post
Replies
10
Views
4K
Replies
4
Views
6K
  • Last Post
Replies
2
Views
638
Replies
3
Views
3K
Replies
1
Views
36K
  • Last Post
Replies
2
Views
3K
  • Last Post
Replies
3
Views
376
Top