Calculating Probability of Excited State of Harmonic Oscillator

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The discussion centers on calculating the probability of a single harmonic oscillator being in its first excited state when in contact with a large solid at a temperature of 150 K. The energy levels of the oscillator are separated by 0.05 eV. Using the Boltzmann factor, the probability is calculated using the formula exp(-e/(kT))/sum(exp(-ne/(kT)), where e is the energy separation, k is the Stefan-Boltzmann constant, and T is the absolute temperature. The relevant probability values were provided, with the correct answer being 0.021.

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  • Understanding of harmonic oscillators and their energy levels
  • Familiarity with the Boltzmann factor and statistical mechanics
  • Knowledge of the Stefan-Boltzmann constant and its units
  • Basic concepts of thermal equilibrium and temperature effects on energy states
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  • Study the derivation and application of the Boltzmann distribution in statistical mechanics
  • Learn about the implications of temperature on quantum states in harmonic oscillators
  • Explore the role of the Stefan-Boltzmann constant in thermodynamic calculations
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This discussion is beneficial for physicists, students of quantum mechanics, and anyone interested in the statistical behavior of quantum systems, particularly in the context of thermal physics and harmonic oscillators.

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Harmonic Oscillator

9. An ideal harmonic oscillator has energy levels separated by a constant 0.05 eV. That
is, the difference between the ground state and the first excited state of this oscillator is
an energy of 0.05 eV. This single oscillator is brought into contact with a large solid
composed of an enormous number of oscillators, and characterized by a temperature of
T=150 K. What is the probability that the single oscillator will be found in its first excited
state?
1. 0.021
2. 0.055
3. 0.098
4. 0.144
5. 0.234
6. 1.000


What relationship should I even start with? Thanks for the help!
 
Last edited:
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This is a simple Boltzmann factor problem.

Recall that the probability of an individual energy level is:

exp(-e/(kT))/sum(exp(-ne/(kT))

where

e is the separation between energy levels
k is the Stefan-Boltzmann constant (make sure you get its units right!)
T is the absolute temperature

in this case, we can neglect all terms n > 1 as they decay rapidly to zero. Also, recal that the energy level for the ground state is 0.

That should help you complete the problem.
 
Last edited:

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