Calculating Weight of Argon in a Cylinder

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SUMMARY

The discussion focuses on calculating the weight of Argon gas in a cylinder under varying pressure and temperature conditions. The initial conditions include a cylinder filled with Argon at 25 °C and 102.4 kPa, with a total weight of 312.50 g. The user attempts to apply the ideal gas law, specifically the equation P1 / (n1 . T1) = P2 / (n2 . T2), to find the number of moles of Argon after the pressure is reduced to 18.2 mmHg and the temperature increased to 35 °C. The final calculation reveals a discrepancy in the expected weight of the gas, indicating a misunderstanding of how to separate the weight of the gas from the total weight of the cylinder.

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  • Understanding of the Ideal Gas Law
  • Knowledge of pressure conversion (mmHg to kPa)
  • Familiarity with molar mass calculations
  • Basic principles of thermodynamics related to gas behavior
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  • Learn how to convert between different pressure units, specifically mmHg and kPa
  • Explore molar mass and its role in calculating gas weights
  • Investigate the effects of temperature on gas volume and pressure
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Students in chemistry or physics, engineers working with gas systems, and anyone involved in gas measurement and calculations will benefit from this discussion.

simonak
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HI,

Here's the question :

A cylinder is fill with Argon (Ar) at 25 °C and 102,4 kPa with a total weight of 312,50 g. The dimension of the cylinder is 32,4 mm of diameter and 1,2162 m long. We remove Argon with a vacuum pump. What will be the total weight of the cylinder if the inside pressure is 18,2 mmHg and the temperature 35 °C ?

First, I don't know why they told us the dimension of the cylinder because the volume will stay the same. Second, I started to convert 18,2 mmHg to 2,42606 kPa, 25 °C to 298 K and 35 °C to 308 K.

After that, I wrote my equation :

P1 / (n1 . T1) = P2 / (n2 . T2)

Now, the only thing that is missing is the n2 so if whe isolate n2 it is :

n2 = 0.179317 mol

and we know that n = m (weight) / M (atomic weight)
so m2 = n2 * M2
...
m2 = 0.179317 mol * 39.948 g/mol
m2 = 7.16337 g
but the answer is
m2 = 310.89 g

The only thing that I'm not really sure is that in the question they told us the weight of the totat cylinder...I use this weight instead of the weight gas.

anyway, maybe it's juste a little detail but if someone could help me it would be very appreciated.

Thank you !
 
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You're given the total weight of the cylinder plus the gas. You can calculate the total weight of the gas initially, right? What should you do from here?
 
I don't know,... they gave me the total weight before and I need the total weight after...I don't know how to find the weight of the gas or the weight of the cylinder...they juste gave me the total.
 
simonak said:
I don't know how to find the weight of the gas

Sure you do. You know the pressure, temperature, and volume of the gas initially, is that enough to determine the mass of the gas (incidently, this should answer your question as to why they told you the volume)? If so, how would you do it?
 
Last edited:

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