Calculation of no. of spectral lines for group of similar atoms

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SUMMARY

The maximum number of spectral lines for a group of 8 hydrogen atoms in the Balmer series, when all are excited to the 6th excited state, is 5. This is derived from the formula [∆n(∆n+1)]/2, which calculates the total possible spectral lines for a single atom. However, since the problem specifically asks for transitions ending at the n=2 state, only transitions that result in spectral lines terminating at this level are counted. Thus, while each atom can theoretically produce multiple transitions, the unique spectral lines for the Balmer series remain limited to 5 due to the identical nature of the hydrogen atoms.

PREREQUISITES
  • Understanding of atomic transitions and energy levels
  • Familiarity with the Balmer series in hydrogen
  • Knowledge of the formula for calculating spectral lines: [∆n(∆n+1)]/2
  • Basic principles of quantum mechanics related to electron excitation
NEXT STEPS
  • Study the derivation and applications of the Balmer series in hydrogen
  • Learn about electron transitions and their impact on spectral lines
  • Explore the concept of energy levels in quantum mechanics
  • Investigate the differences between spectral lines in various atomic models
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Students studying quantum mechanics, physicists interested in atomic structure, and educators teaching atomic theory and spectral analysis.

Prabhu1

Homework Statement


The maximum no of spectral lines for a single atom during it's electron's transition is given by [∆n(∆n+1)]/2 . But I don't seem to arrive at the answer when a group of atoms are present . The question was - What is the maximum number of spectral lines possible for Balmer series when a set of 8 hydrogen atoms are irradiated with light and all are excited to 6th excited state and spectrum is obtained?
2. Homework Equations

[∆n(∆n+1)]/2

The Attempt at a Solution

.[/B]
I am able to calculate the spectral lines for 1 atom which comes out to be 15 . But the answer key says 5 . i am not able to understand how .
 
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Is that the exact full problem statement? If yes, I don't understand the given answer.
 
Your equation tells you about the total possible spectral lines, but the problem asks about the Balmer series.

Also, be careful about the wording of the problem.. What is the 6th excited state?
 
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DrClaude said:
Your equation tells you about the total possible spectral lines, but the problem asks about the Balmer series.

Also, be careful about the wording of the problem.. What is the 6th excited state?
The 7th state
 
Prabhu1 said:
The 7th state
Correct. So how many Balmer series lines do you get?
 
DrClaude said:
Correct. So how many Balmer series lines do you get?
If we come down from each of the higher states directly like 7 ->2 , 6->2 and so on, we will get 5 lines , but there are still other ways to reach the 2nd state , aren't there?
 
Prabhu1 said:
but there are still other ways to reach the 2nd state , aren't there?
Like what?
 
DrClaude said:
Like what?
7 -> 6 ->2 .
 
Prabhu1 said:
7 -> 6 ->2 .
Wasn't that already taken care of who you wrote
Prabhu1 said:
If we come down from each of the higher states directly like 7 ->2 , 6->2 and so on, we will get 5 lines

In other words, where would the 6->2 come from if not from 7->6?
 
  • #10
DrClaude said:
Wasn't that already taken care of who you wroteIn other words, where would the 6->2 come from if not from 7->6?
But still , we are getting a new spectral line for transition from 7 ->6 .
 
  • #11
Prabhu1 said:
But still , we are getting a new spectral line for transition from 7 ->6 .
But that wouldn't be included in balmer series , right?
 
  • #12
Prabhu1 said:
But still , we are getting a new spectral line for transition from 7 ->6 .
Is that line part of the Balmer series?
 
  • #13
Prabhu1 said:
But that wouldn't be included in balmer series , right?
Our messages crossed. Yes, that's the point. You should only count the lines that end on n=2.
 
  • #14
DrClaude said:
Our messages crossed. Yes, that's the point. You should only count the lines that end on n=2.
Okay , got you , silly mistake I did there .thank a ton sir . Btw I really liked your way of helping me , you didn't give out the answer straight away . thanks again .
 
  • #15
Prabhu1 said:
Okay , got you , silly mistake I did there .thank a ton sir . Btw I really liked your way of helping me , you didn't give out the answer straight away . thanks again .
This is the way we do things here.
:welcome:
 
  • #16
But aren't there 8 hydrogen atoms, that will make it 8X5=40
 
  • #17
The atoms are all identical, they have identical spectral lines.
 

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