RICKYtan
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Are there any type of minerals/molecules/elements even solids that when dissolved, in say a glass of room temp water, can raise or lower the temperature? Examples...
Dissolving minerals in water can significantly affect temperature, with various salts exhibiting different thermal behaviors. Calcium Oxide (Quicklime) generates substantial heat upon reaction with water, while salts like Lithium Chloride (LiCl) produce exothermic reactions, raising water temperature. In contrast, Potassium Chloride (KCl) is endothermic, cooling the water. The heat exchange is primarily due to the balance between lattice energy and the energy released during solvation of ions.
PREREQUISITESChemists, educators, and students interested in thermodynamics, particularly those studying the effects of solvation on temperature changes in solutions.
mfb said:Nearly everything, and especially salts, will cool the water while getting dissolved.
Roughly half? Okay, then I misremembered it. I know about the hydration, but I expected it to be smaller for most salts.Borek said:Sorry but no. Many salts (and by many I mean something in a "half" ballpark) have quite a large, negative heat of dissolution. My bet is that you are missing the hydration (or more generally solvation) part - capturing of dipole water molecules by cations and anions. That produces quite a lot of heat, especially when dissolving anhydrous salts.
Individual Ion-ion interactions are significantly stronger than the individual ion-dipole interactions in water solutions, but in solution, you have 4-8 waters tightly bound to each ion, and a few dozen more loosely bound to this inner hydration shell structure, so you can pick up energy pretty quickly in these situations.mfb said:Roughly half? Okay, then I misremembered it. I know about the hydration, but I expected it to be smaller for most salts.