Can dissolving minerals affect water temperature?

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SUMMARY

Dissolving minerals in water can significantly affect temperature, with various salts exhibiting different thermal behaviors. Calcium Oxide (Quicklime) generates substantial heat upon reaction with water, while salts like Lithium Chloride (LiCl) produce exothermic reactions, raising water temperature. In contrast, Potassium Chloride (KCl) is endothermic, cooling the water. The heat exchange is primarily due to the balance between lattice energy and the energy released during solvation of ions.

PREREQUISITES
  • Understanding of heat of dissolution concepts
  • Familiarity with solvation and hydration processes
  • Knowledge of ionic compounds and their properties
  • Basic chemistry principles regarding exothermic and endothermic reactions
NEXT STEPS
  • Research the heat of dissolution for various salts, focusing on LiCl, NaCl, and KCl
  • Study the solvation process and its impact on thermal energy changes
  • Explore practical applications of exothermic reactions in self-heating products
  • Investigate the role of lattice energy in ionic compounds
USEFUL FOR

Chemists, educators, and students interested in thermodynamics, particularly those studying the effects of solvation on temperature changes in solutions.

RICKYtan
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Are there any type of minerals/molecules/elements even solids that when dissolved, in say a glass of room temp water, can raise or lower the temperature? Examples...
 
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Nearly everything, and especially salts, many chemicals will cool the water while getting dissolved. Breaking up the bonds in whatever gets dissolved needs some energy, that energy is taken from heat.
 
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mfb said:
Nearly everything, and especially salts, will cool the water while getting dissolved.

Sorry but no. Many salts (and by many I mean something in a "half" ballpark) have quite a large, negative heat of dissolution. My bet is that you are missing the hydration (or more generally solvation) part - capturing of dipole water molecules by cations and anions. That produces quite a lot of heat, especially when dissolving anhydrous salts.
 
One well known reaction is Calcium Oxide with water . The uncontrolled reaction is quite violent and large amounts of heat are generated .

The reaction can be calmed down a bit if necessary by use of passive additives or by controlling the rate at which the Calcium oxide and water are brought into contact .

This is one of the heat generating reactions used in products like self heating soup .

Calcium Oxide is commonly called Quicklime .
 
The CaO reacts with water beyond simple dissolution. The classic heat of solution experiment is to dissolve the series LiCl, NaCl, KCl in water. LiCl dissolution is very exothermic (water gets very hot), NaCl basically leaves temperature unchanged, and KCl dissolution is quite endothermic (water gets very cold, enough to form frost on the reaction vessel even in small demonstrations). The reason, as @Borek mentioned, is the balance of the salt’s lattice energy with the energy gained by forming a solvation shell of water molecules around the ions.
 
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Borek said:
Sorry but no. Many salts (and by many I mean something in a "half" ballpark) have quite a large, negative heat of dissolution. My bet is that you are missing the hydration (or more generally solvation) part - capturing of dipole water molecules by cations and anions. That produces quite a lot of heat, especially when dissolving anhydrous salts.
Roughly half? Okay, then I misremembered it. I know about the hydration, but I expected it to be smaller for most salts.
 
mfb said:
Roughly half? Okay, then I misremembered it. I know about the hydration, but I expected it to be smaller for most salts.
Individual Ion-ion interactions are significantly stronger than the individual ion-dipole interactions in water solutions, but in solution, you have 4-8 waters tightly bound to each ion, and a few dozen more loosely bound to this inner hydration shell structure, so you can pick up energy pretty quickly in these situations.
 

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