RICKYtan
- 23
- 0
Are there any type of minerals/molecules/elements even solids that when dissolved, in say a glass of room temp water, can raise or lower the temperature? Examples...
The discussion revolves around whether dissolving minerals, specifically salts and other compounds, can affect the temperature of water. Participants explore various examples and the underlying thermodynamic principles, including heat of dissolution and hydration effects.
Participants express differing views on the effects of dissolving salts on water temperature, with no consensus reached on the general behavior of all salts. Some agree on specific examples while contesting the broader claims.
Participants acknowledge the complexity of the dissolution process, including the roles of lattice energy and hydration, but do not resolve the varying effects across different substances.
mfb said:Nearly everything, and especially salts, will cool the water while getting dissolved.
Roughly half? Okay, then I misremembered it. I know about the hydration, but I expected it to be smaller for most salts.Borek said:Sorry but no. Many salts (and by many I mean something in a "half" ballpark) have quite a large, negative heat of dissolution. My bet is that you are missing the hydration (or more generally solvation) part - capturing of dipole water molecules by cations and anions. That produces quite a lot of heat, especially when dissolving anhydrous salts.
Individual Ion-ion interactions are significantly stronger than the individual ion-dipole interactions in water solutions, but in solution, you have 4-8 waters tightly bound to each ion, and a few dozen more loosely bound to this inner hydration shell structure, so you can pick up energy pretty quickly in these situations.mfb said:Roughly half? Okay, then I misremembered it. I know about the hydration, but I expected it to be smaller for most salts.