Can polyester resin eventually cure if it was too cold at first?

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SUMMARY

The discussion centers on the curing process of polyester resin exposed to cold temperatures. Users confirm that while low temperatures can delay curing, the resin can still eventually cure if proper heating methods are applied. Key recommendations include maintaining a stable temperature of 20°C for at least 6 hours and utilizing UV grow lights to accelerate the catalyst reaction. The importance of proper mixing of the catalyst with the resin is emphasized, as poor mixing can significantly hinder the curing process.

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  • Understanding of polyester resin chemistry
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  • Familiarity with temperature effects on chemical reactions
  • Experience with heating methods for resin curing
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This discussion is beneficial for resin artists, DIY enthusiasts, and professionals working with polyester resin who seek to optimize their curing processes and understand the implications of temperature on resin chemistry.

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I mixed polyester resin in around 5°C and overnight it went to -10, and for the next few days it was too cold to cure.
I finally brought in a heater and kept it at about 30C for 3 hours. It still smells like uncured offgassing. Will it ever cure or did the freezing/prolonged cold ruin it and i have to remove it?
 
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I also left the catalyst and resin outside in below freezing temperature, is there a chance i damaged it?
 
mess said:
I also left the catalyst and resin outside in below freezing temperature, is there a chance i damaged it?
No. You preserved it.
The problem with cold resin is mixing the catalyst into the thick cold resin. Poor mixing requires longer for the catalyst to diffuse or migrate through the mix. Diffusion is very poor at low temperatures. The heat generated by the reaction will accelerate the reaction, unless that heat is rapidly lost to a cold environment, in which case you must wait for the environment to warm.
I once waited for a week during a cold snap for polyester resin to set. It took another week before I could remove it from the mold.
 
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Baluncore said:
No. You preserved it.
The problem with cold resin is mixing the catalyst into the thick cold resin. Poor mixing requires longer for the catalyst to diffuse or migrate through the mix. Diffusion is very poor at low temperatures. The heat generated by the reaction will accelerate the reaction, unless that heat is rapidly lost to a cold environment, in which case you must wait for the environment to warm.
I once waited for a week during a cold snap for polyester resin to set. It took another week before I could remove it from the mold.

Its been about 3 weeks now and it still stinks :/ I've since put a IR heat lamp on it for about 12 hours total, with no change in smell. it smells like freshly mixed resin, not as strong, but it still smells when i go up close to it.
 
Has it gelled yet, or does it still flow? Is it like rubber?

It will continue to smell for quite a while. If it smells different to plain resin, then it is reacting, and you did remember to put the catalyst in. The smell will permeate grains, flour and similar products.

What is the size and shape of the item? If it is a thin laminate it will reflect or radiate as much heat as you can provide. Maybe you need to make a polythene tunnel or tent, supported by hoops or wires. Use a fan heater and circulate air continuously throughout the chamber. Maintain a stable 20°C for 6 hours.

Just an idea. You have tried IR, but you might benefit from “UV grow lights”. Catalyst reacts very rapidly in direct sunlight due to the UV.
 

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