Hmm, I think we should be very careful when discussing wave/particle duality and what exactly this means.
Wave-particle duality generally means that the electron acts like a particle for some experiments and like a wave for others. This means, in simplified terms, if I am looking for particle-properties such as mass, the electron will act as a particle. If I am looking for wave-like properties such as diffraction, the electron will act like a wave.
If you try to measure the mass of the electron, you get a definite mass because you are looking for a particle-tied property and the electron will act as a particle for this test! You will never measure the electron to have zero mass, because the electron will NOT act like a wave for a mass measurement.
I'm trying to keep this discussion close to High-school level, so at higher levels of understanding, the picture is more complicated. I will digress a little bit into the more complicated picture, but if you don't understand it at this point, don't worry. You will, once you study QM at a deeper level. The wave is, as I mentioned, a probability wave. The particle is described by a wave-function, and this wave-function is NOT physical in any sense. You can't make any measurements on this wave-function. So it doesn't make sense to try to measure the "mass" of this wave-function. All you can do is measure many electrons prepared in the same state to try to get a feel for the probability distribution of the electrons. The double slit experiment, for example if you release one electron at a time, each detection event is particle-like. You see 1 electron at one detector, and then 1 electron at another detector. You never detect some sort of "wave". Where the wave characteristics come in is when you get many detections, you will see a diffraction pattern IN your detections which would not arise classically for particles. It is therefore easier to describe the sum total diffraction phenomenon in terms of waves.