Can s oribtal electrons only drop to other s orbitals?

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Homework Help Overview

The discussion revolves around the behavior of electrons in s orbitals, particularly focusing on transitions between energy states and the implications of quantum numbers in these transitions.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants explore the conditions under which an electron in an s orbital can transition to other orbitals, questioning the allowed transitions based on quantum numbers and symmetry considerations.

Discussion Status

There is an ongoing exploration of the rules governing electron transitions, with some participants suggesting that transitions from s to p orbitals are allowed, while others question the possibility of transitions back to s orbitals. The discussion reflects differing interpretations of quantum mechanical principles.

Contextual Notes

Participants are considering the implications of the dipole operator's symmetry and the quantum number constraints on allowed transitions, indicating a need for clarity on these foundational concepts.

friendbobbiny
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Just a thought:

The momentum quantum number given for s states is l = 0. If an S state electron dropped in energy, and emitted a photon with l = 1, what would take place?


Am I correct that the electron could only drop to a lower l = 0 (an S state) orbital?
 
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Dipole transitions from s are only allowed to p orbitals.
 
Why can't a drop to s take place? I infer that a drop to p(l = 1) can take place because \Delta l = 1.
 
The dipole operator is odd, so it only gives overlap between states with odd and even symmetry.
 

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