Can we prove the existence of energy levels in an atom and why is it important?

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Discussion Overview

The discussion revolves around the existence of energy levels within an atom and the methods to demonstrate this concept. It touches on theoretical implications, experimental evidence, and historical context related to atomic physics.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested, Experimental/applied, Historical

Main Points Raised

  • One participant inquires about direct demonstrations of atomic energy levels.
  • Another suggests examining the spectrum of ionized gas using a diffraction grating spectrometer as a method to observe energy levels.
  • A participant questions how the emission of spectra serves as proof of energy levels and seeks clarification on the reasoning behind this connection.
  • It is noted that each spectrum at a specific angle corresponds to emitted energy, linking it to atomic energy levels, and that understanding this requires algebra and geometric descriptions.
  • Another approach mentioned involves sending a beam of electrons into a gas to study scattering, highlighting inelastic collisions that correspond to energy level differences, referencing the Franck-Hertz experiment for further details.
  • A participant discusses the quantization of energy, relating it to the historical "ultraviolet catastrophe" and the inadequacies of classical physics in explaining atomic phenomena, which led to the development of quantum theory.

Areas of Agreement / Disagreement

Participants present multiple methods and perspectives on demonstrating atomic energy levels, indicating that there is no consensus on a singular approach or understanding of the implications of quantization.

Contextual Notes

Some discussions involve assumptions about the necessity of quantization and the historical context of atomic theory, which may not be universally accepted or fully resolved within the conversation.

Delzac
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how can we directly demonstrate the existence of energy level within an atom??
 
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Look at the spectrum of ionized gas, such as from a discharge tube, using, for example, the diffraction grating spectrometer.

Zz.
 
so atoms can emit spectra is the proof ? y so, how does that proof?
 
Delzac said:
so atoms can emit spectra is the proof ? y so, how does that proof?

Each of the spectra, at a specific angle, corresponds to the energy that it was emitted from. From there, you get correspondence with the atomic energy level.

You may want to look this up and see why this is so, because the theory requires algebra and geometrical description.

Zz.
 
Or you can send a beam of electrons with a kinetic energy of a few tens of eV into a gas, and study the way they scatter via collisions. It becomes apparent that there are inelastic collisions in which atoms absorb certain fixed amounts of kinetic energy, corresponding to the differences between energy levels. Do a Google search on "Franck-Hertz experiment" for more details.
 
what you are essentially asking is why energy must be quantized...

..the answer is that this avoids the "ultraviolet catastrophe" where classical physics predicted that if there is an non-quantized energy continuum then blackbody radiation would have infinite energy. This was one of the first historical clues that something was wrong with describing atomic phenomena classically, and led to quantum theory - which of course is experimentally validated from the spectra that others have mentioned above.
 

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