Central Equation Derivation: NxN Matrix?

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SUMMARY

The central equation derivation for a NxN matrix is established through the relationship $$ (\lambda_k - \epsilon)C_k + \Sigma_G U_G C_{k-G} = 0 $$, which couples coefficients across reciprocal lattice vectors. This equation is not merely a single line but represents a set of equations that couples coefficients Ck, Ck−G, Ck−G', and Ck−G'' for a fixed k in the first Brillouin zone. The confusion arises from interpreting C(k) as a vector; it is, in fact, a collection of Fourier coefficients that can be expressed in matrix form for solution.

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  • Understanding of solid state physics concepts, particularly Brillouin zones.
  • Familiarity with Fourier transforms and their application in wavefunctions.
  • Knowledge of matrix algebra and its application in solving systems of equations.
  • Basic principles of quantum mechanics, especially the Schrödinger equation in periodic potentials.
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  • Study the derivation of the central equation in "Solid State Physics" by Ashcroft and Mermin.
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  • Explore matrix methods for solving linear equations in quantum mechanics.
  • Investigate the implications of Fourier coefficients in wavefunction analysis.
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Students and researchers in solid state physics, particularly those studying electronic properties of materials and the mathematical foundations of quantum mechanics.

semc
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I went through the derivation for the central equation

$$(\lambda_k - \epsilon)C_k + \Sigma_G U_G C_{k-G} = 0$$

and everywhere I look everybody just says this is a NxN matrix. I don't see how this is true. Isn't this just a one line equation with summation across all reciprocal lattice? I don't understand why at one value of k we get NxN matrix. Any help is greatly appreciated!
 
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Yeah this is what I found but the central equation is
$$ \frac{\hbar^2k^2}{2m} C_k + \sum_{G}^{} V_GC_{k-G}=EC_k$$
so shouldn't I just have
$$ \frac{\hbar^2k^2}{2m} C_k + V_0C_{k-g} + V_0C_{k+g}=EC_k$$
for G=ng and $$ V=V_0e^{igx} +V_0e^{-igx} ?$$
How do you get the other equations
$$ \frac{\hbar^2(k-g)^2}{2m} C_{k-g} + V_0C_{k-2g} + V_0C_{k}=EC_{k-g}$$
 
The "central equation" is a set of equations. For a fixed k in the first Brillouin zone, this set of equations for all reciprocal lattice vectors G couples those coefficients Ck , CkG , CkG' , CkG'' ,... whose wave vector differ from k by a reciprocal vector. Equation (107) in [1] which follows the presentation in the textbook “Solid State Physics” by Neil W. Ashcroft and N. David Mermin should illustrate the meaning of the "central equation". Have a look at [2], too.

[1] [PDF]Introduction to Solid State Physics
[2] [PDF]7.6 The Schrödinger equation of electron in a periodic potential
 
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Well I read the book by ashcroft and mermin and [2] before. Everybody just says that the C(k) couples to C(k+G). Are they referring to the coupling via V0? I really don't see where the other equations come from
 
I guess I am asking why is C(k) a vector? Isn't C(k) just the Fourier coefficient of the wavefunction?

upload_2018-9-7_14-6-30.png
 

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semc said:
I guess I am asking why is C(k) a vector?

C(k) isn't a vector. You simply write the set of equations which have to be solved in a matrix form.
 
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