This is a good question where one can easily get confused. For the first case, draw a free body diagram of the forces acting on the car...its weight acts straight down, and the normal force acts perpendicular to the banked road surface. The centripetal direction of the curve's radius is along the horizontal x axis. Since you are interested in centripetal forces and centripetal acceleration, you'll want to break up your Normal force into its horizontal x and vertical y components. The weight force will have no x component, which is a good thing.
For part 2, the weight and normal forces act in a vertical direction, and only the friction force acts in the horizontal (centripetal) direction, so you son't have to break up any forces into components, since they already are given in their x or y directions, which is nice.
Note that on many inclined plane problems , where it is convenient to choose the x-axis as parallel to the slope of the plane, then you want to break up the weight force into components parallel and perpendicular to the plane. It takes a lot of practice to get familiar with all this.