Ceramic that is electrical conductor?

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Discussion Overview

The discussion revolves around the possibility of finding a ceramic material that serves as both a high thermal insulator and a good electrical conductor. Participants explore the relationship between thermal insulation and electrical conductivity, questioning whether these properties are mutually exclusive.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant inquires whether high thermal insulators like ceramics can also be good electrical conductors, suggesting a potential conflict between these properties.
  • Another participant mentions aerographite as a possible candidate, linking to an external source for further information.
  • It is noted that some ceramics can be semiconductors or conductors if they are doped, indicating that the relationship between thermal and electrical properties may not be straightforward.
  • A participant discusses the Wiedeman-Franz law, suggesting that if electrical conduction is due to free electrons, there may be a constant ratio between thermal and electrical conductivity. They also mention that charge carriers responsible for electrical conduction might also conduct heat.
  • The discussion highlights that the definition of "good" and "bad" in terms of thermal and electrical conduction is subjective and may vary based on context.
  • Concerns are raised about composite materials like aerographite, which may exhibit reduced thermal and electrical conductivity due to their structure.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between thermal insulation and electrical conductivity, with no consensus reached on whether these properties can coexist in ceramics or similar materials.

Contextual Notes

The discussion includes assumptions about the mechanisms of electrical conduction and the definitions of conductivity terms, which remain unresolved.

fysik
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hello!

is there a high thermal insulator material, like ceramics, that is also a good electricity conductor?

or these two things, thermal insulation and electrical conductivity, are mutually exclusive?

thanks!
 
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Although it's thermal properties come partly from trapping air and/or pore size.

Some ceramics are semiconductors or conductors if doped.
 
As long as the electrical conduction is due to free electrons, the ratio between the two conductivity is relatively constant (Wiedeman-Franz law).
You may have a ceramic with electric conduction due to other mechanisms (like "hopping"). But I don't see why the carriers of charge responsible for electrical conduction won't conduct heat as well.
In the end, it depends on what you mean by "good" and "bad" when applied to the two properties (thermal and electrical conduction).
A composite like aero-graphite may have a thermal conductivity lower than that of a bloc of graphite of the same size. But the electrical conductivity will be also reduced by the air in the structure.
 

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