Chemical reactions to depict Le Chatelier's Principle (Temperature)

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SUMMARY

The discussion focuses on Le Chatelier's Principle as it relates to temperature changes in endothermic reactions. It establishes that lowering the temperature decreases the forward reaction rate more significantly, leading to a shift in the equilibrium constant (K) to the left. The Van't Hoff equation, $$\frac{d\ln{K}}{dT}=\frac{\Delta H}{RT^2}$$, is cited to illustrate the temperature dependence of the equilibrium constant, where ##\Delta H## represents the standard heat of reaction. This relationship confirms that both forward and reverse reaction rates decrease, affecting the equilibrium position.

PREREQUISITES
  • Understanding of Le Chatelier's Principle
  • Knowledge of endothermic and exothermic reactions
  • Familiarity with the Van't Hoff equation
  • Basic concepts of chemical equilibrium
NEXT STEPS
  • Study the implications of temperature changes on exothermic reactions
  • Explore the application of the Van't Hoff equation in various chemical systems
  • Investigate the relationship between reaction enthalpy (ΔH) and equilibrium constants
  • Learn about the effects of pressure and concentration changes on chemical equilibria
USEFUL FOR

Chemistry students, chemical engineers, and researchers interested in thermodynamics and reaction kinetics will benefit from this discussion.

angela107
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I've been tasked to research the temperature component of Le Chatelier’s Principle. I need to include at least one chemical reaction (ideally supporting my discussion). I decided to talk about endothermic and exothermic reactions.
If an endothermic reaction has a lower temperature, since the forward reaction rate decreases more, the reaction should produce more energy to compensate for the decreased energy and raise the rate of the forward reaction until it reaches equilibrium with the reverse reaction. Is this saying that overall the rates of both forward and reverse reaction decrease and K will shift left compared to the original K?
 
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The Van't Hoff equation for the temperature dependence of the equilibrium constant is given by:
$$\frac{d\ln{K}}{dT}=\frac{\Delta H}{RT^2}$$where ##\Delta H## is the standard heat of reaction at temperature T.
 
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