Classical Canonical Partition Function in Two Dimensions

In summary: I had thought that the potential, U(r), was zero for r > ro, which would mean that ##e^(-U) = 1## and thus the second integral would be zero. However, if the potential is only zero at r = ro, then the second integral would not be zero and the expression for Z would be correct.In summary, the conversation discusses the calculation of Z, the total partition function, for a single particle in a potential well. The final expression for Z is determined to be N*(1/h^2)*((m/beta)*R)^N. The average number of particles and the average potential energy are also calculated. A minor error is pointed out regarding the dimensions of the area element, but otherwise the
  • #1
Diracobama2181
75
2
Homework Statement
Consider a classical gas in two dimensions trapped inside a circle of radius $R$ and a potential well given by
$$U= \begin{cases}
-U_0 & r<r_0 \\
0 & r\geq r_0 \\
\end{cases}
$$
Assume $$r_0<<R$$.
Find the canonical partition function for this system. Then find the average number of particles in the well and the average potential energy of the particles.
Relevant Equations
$$Z=\frac{1}{h^2}\int e^{-\beta H(p,q)}d^2pd^2q$$
$$H=\frac{P^2}{2m}+U(r)$$
For a single particle,
$$Z=\frac{1}{h^2}\int_{-\infty}^{\infty} e^{-\beta \frac{P^2}{2m}}d^2p \int e^{-U(r)}drd\theta=
\frac{1}{h^2}(\frac{2\pi m}{\beta}) 2\pi [\int_{0}^{r_0}e^{U_0}dr+\int_{r_0}^{R}dr]$$
$$
=\frac{1}{h^2}(\frac{2\pi m}{\beta}) 2\pi [e^{U_0}(r_0)+(R-r_0)]=\frac{\pi R^2}{h^2}(\frac{2\pi m}{\beta})2\pi [e^{U_0}\frac{(r_0)}{\pi R^2}+(\frac{R}{\pi R^2}-\frac{r_0}{\pi R^2})] \approx \frac{1}{h^2}(\frac{2\pi m}{\beta})2\pi R
$$
Thus,
$$Z_{tot}=(\frac{1}{\hbar^2}(\frac{m}{\beta})R)^N$$.
For the average number of particles in the well, I would assume it would be
$$<n>=\frac{N\frac{1}{h^2}\int e^{-\beta(\frac{P^2}{2m}-U_0)}d^2 p d^2q} {Z}=\frac{N\frac{1}{h^2}(\frac{2\pi m}{\beta}) 2 \pi \int_0^{r_0} e^{\beta U_0}dr} {Z}$$
and
$$<U>=\frac{N (-U_0)\frac{1}{h^2}(\frac{2\pi m}{\beta}) 2 \pi \int_0^{r_0} e^{\beta U_0}dr} {Z}$$
Would appreciate if anyone could confirm whether I'm on the right track. Thanks!
 
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  • #2
If the potential is zero for r > ro wouldn't that mean that your second integral from ro to R is zero? You integrated "1" when the potential states zero in this interval. Other than this everything else seems fine.
 
  • #3
Diracobama2181 said:
For a single particle,
$$Z=\frac{1}{h^2}\int_{-\infty}^{\infty} e^{-\beta \frac{P^2}{2m}}d^2p \int e^{-U(r)}drd\theta$$
You wrote the area element ##d^2q## as ##dr d\theta##. But ##dr d\theta## doesn't have the dimensions of area.

Otherwise, I think you're on the right track.
 
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  • #4
Vitani1 said:
If the potential is zero for r > ro wouldn't that mean that your second integral from ro to R is zero? You integrated "1" when the potential states zero in this interval. Other than this everything else seems fine.

Are you referring to the last integral in the following expression for ##Z##?

Diracobama2181 said:
$$Z=\frac{1}{h^2}\int_{-\infty}^{\infty} e^{-\beta \frac{P^2}{2m}}d^2p \int e^{-U(r)}drd\theta=
\frac{1}{h^2}(\frac{2\pi m}{\beta}) 2\pi [\int_{0}^{r_0}e^{U_0}dr+\int_{r_0}^{R}dr]$$

The "1" looks Ok to me. ##e^0 = 1##.
 
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  • #5
My apologies.
 
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What is the classical canonical partition function in two dimensions?

The classical canonical partition function in two dimensions is a mathematical tool used in statistical mechanics to calculate the thermodynamic properties of a system consisting of particles confined to a two-dimensional space.

How is the classical canonical partition function in two dimensions calculated?

The classical canonical partition function in two dimensions is calculated by summing over all possible microstates of the system, weighted by their corresponding Boltzmann factors. This can be expressed mathematically as Z = ∑e-βH, where Z is the partition function, β is the inverse temperature, and H is the Hamiltonian of the system.

What is the significance of the classical canonical partition function in two dimensions?

The classical canonical partition function in two dimensions allows us to calculate various thermodynamic properties of a system, such as the internal energy, entropy, and free energy. It also provides a connection between the microscopic properties of a system and its macroscopic behavior.

What are the assumptions made in the classical canonical partition function in two dimensions?

The classical canonical partition function in two dimensions assumes that the particles in the system are non-interacting and that the system is in thermal equilibrium. It also assumes that the particles are distinguishable and that the energy levels of the system are discrete.

Can the classical canonical partition function in two dimensions be extended to higher dimensions?

Yes, the classical canonical partition function can be extended to systems in higher dimensions. However, the calculations become more complex as the number of dimensions increases.

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