Clausius-Mossotti Equation and Dielectric Constants of Air

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SUMMARY

The discussion centers on the application of the Clausius-Mossotti equation to calculate the polarizability of air, denoted as α. The user initially calculated α using the formula α = (3 ε₀ M_air / (ρ_air N_a)) * ((K_air - 1) / (K_air + 1)), but arrived at an incorrect value of 2.902 * 10^{-43}. The correct value, as per the textbook, is α = 9.7 * 10^{-41}. Key errors identified include the incorrect molar mass of air and a misunderstanding of the Clausius-Mossotti equation's denominator.

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Blastrix91
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Homework Statement



http://img809.imageshack.us/img809/5676/unavngivetk.png

Additional table info:

The molarmass ##M_{air}## is ##29 * 10^{-3} g/mol = 29*\frac{10^{-3}}{1000} kg/mol##
The mass density ## \rho_{air} ## is ##1.3 kg/m^{3}##
The dielectric constant ## K_{air}## is 1.00059

My teacher told me to consider the air as 1 molecule.

Homework Equations



http://img94.imageshack.us/img94/1667/unavngivet2w.png

The Attempt at a Solution



Here is my approach:

Basically it is only N we need which is molecules per volume:

N = \frac{Molecules}{V} = \frac{N_a n}{V} = \frac{m}{M_{air}} \frac{N_a}{V} = \frac{\rho_{air}V}{M_{air}} \frac{N_a}{V} = \frac{\rho_{air}N_a}{M_{air}}

\alpha = \frac{3 \varepsilon_0 M_{air}}{\rho_{air}N_a} \frac{K_{air}-1}{K_{air}+1}

Inserting the values:\frac{3(8.854*10^{-12})(29*\frac{10^{-3}}{1000})}{1.3(6.022*10^{23})} * \frac{1.00059 - 1}{1.00059 + 1} = 2.902 * 10^{-43}

The answer in the back of my book says it is supposed to be: ##\alpha = 9.7 * 10^{-41}##

Can any of you guys spot where I did wrong? (The table values were some I got from my teacher and if my approach is right, then he might have wrote them wrong)
 
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Blastrix91 said:
The molarmass ##M_{air}## is ##29 * 10^{-3} g/mol = 29*\frac{10^{-3}}{1000} kg/mol##

A quick Google check on the molar mass of air will show an error in this value.

You used
\alpha = \frac{3 \varepsilon_0 M_{air}}{\rho_{air}N_a} \frac{K_{air}-1}{K_{air}+1}

but the denominator of ##K_{air}+1 ## does not agree with the form of the Claussius-Mossotti equation that you quoted.Also, does your answer for ##\alpha## correspond to a molecule or an atom?
 
Last edited:
All three things you pointed out gave me the right answer. Thank you ^^
 

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