Comparing Reactivity: F, Cl, and Br in the Periodic Table

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Discussion Overview

The discussion centers around the reactivity of the elements fluorine (F), chlorine (Cl), and bromine (Br) in the periodic table. Participants explore the criteria for determining reactivity, including concepts of electropositivity, electronegativity, and electron shell configuration.

Discussion Character

  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • One participant suggests bromine is more reactive due to having three electron shells, which might allow it to lose electrons more easily.
  • Another participant counters that fluorine is more reactive because it can gain electrons more effectively, given its two electron shells.
  • There is a question about whether reactivity should be classified based on electropositivity or electronegativity, indicating confusion over the criteria used.
  • A later reply proposes that if a mixture of elements that prefer to gain and lose electrons exists, the reactivity could depend on the number of electron shells, suggesting a different perspective on reactivity.
  • One participant argues that comparing reactivity between elements on opposite sides of the periodic table, such as caesium and fluorine, is not meaningful as they react with different substances.

Areas of Agreement / Disagreement

Participants express differing views on the criteria for determining reactivity, with no consensus reached on whether to prioritize electron gain or loss, or how to compare elements with different properties.

Contextual Notes

Participants have not resolved the assumptions regarding the definitions of reactivity, and there are unresolved questions about the implications of electron shell configurations on reactivity.

Anithadhruvbud
Messages
84
Reaction score
6

Amoung three elements F,CL,Br which is more reactive? I guessed it to be bromine because it has three shells and hence when we go down the group on the basis of their shells bromine will easily lose electrons.
But the book says it is fluorine since it can easily gain electrons.And how can that be? Shouldn't we classify something as reactive on the basis of electropositivity?
Looks odd because another answer to a question similar to this answered on the basis of electronegativity.
What exactly is the criteria I should use here?
 
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All three elements "prefer" to accept an additional electron, instead of donating electrons: they just need one more for a noble gas configuration. And fluorine does so much better because it just has two shells.
 
mfb said:
All three elements "prefer" to accept an additional electron, instead of donating electrons: they just need one more for a noble gas configuration. And fluorine does so much better because it just has two shells.
Got it! Thank you! But what if there was a mixture of elements which preferred to gain and lose electrons? In that case,which is more reactive?
It is justified if all three preferred to lose electrons because the one which has more shells will be more reactive,just opposite to the case of non metallic nature,isn't it?
 
It doesn't make much sense to compare reactivity of materials on the opposite side of the spectrum, e. g. caesium with fluorine. In general they will react with different things.
 

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