Condition for formation of ionic bond

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Discussion Overview

The discussion revolves around the conditions for the formation of ionic bonds, specifically addressing the size relationship between cations and anions. Participants explore whether the textbook's assertion that "the cation should be large and the anion should be small" is accurate, and how this relates to the structure of ionic lattices, using NaCl as a reference point.

Discussion Character

  • Debate/contested

Main Points Raised

  • One participant cites their textbook stating that the cation should be large and the anion small, questioning its validity in light of the NaCl lattice structure.
  • Another participant agrees that the textbook's condition seems incorrect, asserting that there is no such condition for ionic bond formation.
  • A participant emphasizes that all ionic substances exist as ionic crystals rather than as single ionic bonds or molecules.
  • Some participants suggest that while size may not directly influence the formation of ionic bonds, it could affect the type of lattice structure formed.

Areas of Agreement / Disagreement

Participants express disagreement regarding the textbook's claim about cation and anion sizes, with some asserting that size does not matter in the context of ionic bond formation. However, there is no consensus on the implications of size for lattice structures.

Contextual Notes

Participants note that the discussion does not resolve the relationship between ionic bond formation and lattice structure, highlighting the complexity of the topic.

gracy
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In my textbook one of the conditions for formation of ionic bond is given as
The cation should be large and anion should be small
But in the image of Nacl lattice structure ,we can see that it is other way around

I am not getting the reason,Is my textbook wrong ?
Or it has something to do with difference between ionic bond and lattice structure.I mean the picture I have attached is of crystal lattice not of single ionic bond between Sodium and chloride ion.

Thanks.
 
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gracy said:
But in the image of Nacl lattice structure ,we can see that it is other way around
upload_2015-4-19_12-56-42.jpeg
 
gracy said:
In my textbook one of the conditions for formation of ionic bond is given as
The cation should be large and anion should be small

Pure nonsense, no such condition.

Additionally, there is no such thing as a "single ionic bond" and a "single ionic molecule". All pure ionic substances exist only as ionic crystals (well, is some highly exotic conditions you can observe single molecules, it doesn't change the validity of the general statements).
 
Borek said:
Pure nonsense, no such condition.
That means my textbook is wrong.
 
Looks like.
 
And there is no such condition as
anion should be large and cation should be small either,right?
 
No, sizes don't matter at all.

They matter when it comes to the type of the lattice that they will build, but that's another story.
 

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