Constraints on potential for normalizable wavefunction

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SUMMARY

In one-dimensional quantum mechanics, a wavefunction is non-normalizable if the energy E exceeds the potential V at infinity (V(∞)) or negative infinity (V(-∞)). This results in a wavefunction that diverges, preventing the integral of its square from being finite. Necessary and sufficient conditions for a potential to yield normalizable solutions include being bounded from below and having an upper bound, along with properties that ensure the wavefunction approaches zero at infinity. Specifically, potentials must exhibit a non-zero gradient at boundaries or possess periodicity that facilitates this decay.

PREREQUISITES
  • Understanding of the Schrödinger equation
  • Familiarity with concepts of wavefunctions and normalizability
  • Knowledge of potential energy functions in quantum mechanics
  • Basic principles of calculus, particularly regarding limits and integrals
NEXT STEPS
  • Study the implications of bounded potentials in quantum mechanics
  • Explore the mathematical treatment of wavefunctions in the context of the infinite square well
  • Investigate the conditions for normalizability in higher-dimensional quantum systems
  • Learn about the role of periodic potentials in quantum mechanics and their effects on wavefunctions
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Quantum physicists, graduate students in physics, and anyone studying the mathematical foundations of quantum mechanics will benefit from this discussion.

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We know that in one dimension if ##E>V(\infty)## or ##E>V(-\infty)## then the resulting wave function will not be normalizable. The basic argument is that if ##E>V(\infty)##, then a stationary solution to the Schrödinger equation will necessarily have a concavity with the same sign as the solution itself for all ##x## greater than some value ##a##. So if the resulting wavefunction was positive after ##a##, then the wavefunction would also be concave up and curve away from the x-axis. Then the integral of the squared wavefunction would tend towards infinity since the wavefunction would never again go to ##0##. A similar argument can be made if the wavefunction was negative after ##a## and again for ##E>V(-\infty)##. We don't have this problem with the infinite square well or simple harmonic oscillator because the potentials go to infinity at ##\pm \infty##.

In short, my question is this: What are necessary and sufficient conditions for a potential to generate normalizable solutions?

I would prefer to keep things simple with a one-dimensional treatment that doesn't need to be as rigorous as say a functional analysis proof (so maybe constrain ourselves to potentials that are at least C2). But after that's accomplished, I definitely wouldn't mind a more advanced discussion.
 
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The necessary and sufficient conditions for a potential to generate normalizable solutions are that the potential must be bounded from below, meaning that the potential must have a finite limit as x approaches infinity, and also that the potential must have an upper bound, meaning that the potential must have a finite limit as x approaches negative infinity. In addition, the potential must have properties that allow the wavefunction to fall off to zero at infinity, such as having a non-zero gradient at the boundaries, or having a periodicity that allows it to repeat in a way that it reaches zero at infinity. This is because the integral of the square of the wavefunction must be finite for the wavefunction to be normalizable.
 

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