CrusaderSean
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I'm having problem with griffith QM problem 4.43:
Construct the spatial wave function for hydrogen in the state n = 3, l =2, m = 1. Express your answer as a function of r, \theta, \phi, and a (the Bohr radius) only.
My prof. gave hints about radial wave function, but I have no idea how to construct spherical harmonics from scratch. The book only shows spherical harmonic are eigenfunctions of L^2 and L_z, not how you can generate them with L_{\pm} operators. So is there a way to generate spherical harmonics with operators similar to harmonic oscillator operator method? I guess more specifically, is there a way to get spherical harmonics for Y_{l=2}^{m=0}? I know I can apply L_{+} to get Y_{l=2}^{m=1}.
edit: nevermind, looks like Griffith made generating spherical harmonics into problem 4.22 as oppose to showing how to do it. that was very tricky of my professor to sneak another problem into homework.
edit2: I'm having problems with 4.22...
denoting spherical harmonics as Y_{l}^{m}(\theta,\phi)=f(\theta)g(\phi), solve for g(\phi) first.
L_{z}Y_{l}^{l}=\hbar l Y_{l}^{l}
g(\phi)=e^{i l \phi} as expected.
now for f(\theta)
L_{+}Y_{l}^{l}=0
where L_{+}=\hbar e^{i \phi}(\partial_{\theta}+i \cot \theta \partial_{\phi})
solving this I get
\ln f(\theta) = \frac{l}{\hbar}e^{i \phi} \ln \sin \theta
which doesn't look right... it's an exponential of an exponetial... any clues as to what I did wrong?
Construct the spatial wave function for hydrogen in the state n = 3, l =2, m = 1. Express your answer as a function of r, \theta, \phi, and a (the Bohr radius) only.
My prof. gave hints about radial wave function, but I have no idea how to construct spherical harmonics from scratch. The book only shows spherical harmonic are eigenfunctions of L^2 and L_z, not how you can generate them with L_{\pm} operators. So is there a way to generate spherical harmonics with operators similar to harmonic oscillator operator method? I guess more specifically, is there a way to get spherical harmonics for Y_{l=2}^{m=0}? I know I can apply L_{+} to get Y_{l=2}^{m=1}.
edit: nevermind, looks like Griffith made generating spherical harmonics into problem 4.22 as oppose to showing how to do it. that was very tricky of my professor to sneak another problem into homework.
edit2: I'm having problems with 4.22...
denoting spherical harmonics as Y_{l}^{m}(\theta,\phi)=f(\theta)g(\phi), solve for g(\phi) first.
L_{z}Y_{l}^{l}=\hbar l Y_{l}^{l}
g(\phi)=e^{i l \phi} as expected.
now for f(\theta)
L_{+}Y_{l}^{l}=0
where L_{+}=\hbar e^{i \phi}(\partial_{\theta}+i \cot \theta \partial_{\phi})
solving this I get
\ln f(\theta) = \frac{l}{\hbar}e^{i \phi} \ln \sin \theta
which doesn't look right... it's an exponential of an exponetial... any clues as to what I did wrong?
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