What rate are we talking about here?
Are you asking why the hollow sphere cools down from a higher temperature to a lower temperature in less time than a solid sphere? In which case you have the answer from the previous posts - a solid sphere has more mass to cool down.
Or are you asking why the hollow sphere looses more heat energy per degree in temperature differential between the sphere and the air - assuming it is in air - than the solid sphere. And in this case, the rates are the same - both spheres lose the same amount of heat energy with regards to the temperature differential at the surface.
The solid sphere will thus take longer to cool since it has more heat energy to lose. Realize that heat energy from the solid sphere is moving from the interior to the surface via the temperature differential from the surface to the interior. A hollow sphere has no "heat" in its interior.