Creating Entropy by Mixing Hot and Cold Water

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SUMMARY

The discussion focuses on calculating the change in entropy when mixing 50 liters of hot water at 55 degrees Celsius with 25 liters of cold water at 10 degrees Celsius. The initial calculations yielded a total entropy change of 11656.4 J/K. However, it was pointed out that the equations used were incorrect as they did not account for the varying temperatures during the mixing process. The correct approach involves integrating the entropy change for each water component as they reach thermal equilibrium.

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  • Understanding of thermodynamic principles, specifically entropy.
  • Familiarity with the calorimetric equation Q = mc·dT.
  • Knowledge of integration techniques for variable temperature calculations.
  • Basic concepts of heat transfer and thermal equilibrium.
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Homework Statement



In order to take a nice warm bah, you mix 50 liters of hot water at 55 degrees celsuis wti h25 liters of cold water at 10 degrees celsius . how much new entropy have you created by mixing the water?


Homework Equations


Possible equations:
dS=Q/T:
Q=m*c*delta(T)
Q=m*L

The Attempt at a Solution



First, I need to convert the volumes of water into mass by multiplying the density of water by Volume.

m(hot)=(50 L)*(1.00 g/cm^3)= 50000 grams.
deltaS(hot)=(50000 g)*(4.18 J/(K*g))*(328 K-283 K)/(328 K)= 28673 J/K
m(cold)=(25 L)*(1.00 g/cm^3)= 25000 grams
deltaS(cold)=(25000 g)*(4.18 J/(K*g))*(283 K - 328 K)/(283 K)= -16616.60 J/K

deltaS(new)=deltaS(cold)+deltaS(hot)= (-16616.60 J/K)+(28273 J/K)= 11656.4 J/K
 
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Benzoate said:

Homework Equations


Possible equations:
dS=Q/T:
Q=m*c*delta(T)

OK, there's a little problem with one of your equations. The differential entropy is

dS = dQ/T .

If you put that together with the calorimetric equation, which will give you

dQ = mc·dT ,

you have dS = mc · (dT / T).

When the hot water is cooling to 40º C (283 K) and the cold water warming to that equilibrium temperature, the temperatures of the components are not constant. So you will have to integrate to find the change in entropy of each component. The sum should be positive, but will be different from the value you have presently...
 

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