De Broglie wavelength of nitrogen molecules

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Homework Help Overview

The discussion revolves around calculating the average de Broglie wavelength of nitrogen molecules at room temperature using principles from statistical mechanics. The original poster presents a formula derived from kinetic energy and momentum relationships.

Discussion Character

  • Exploratory, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to derive the de Broglie wavelength using the relationship between kinetic energy and momentum, questioning the unit consistency in their calculations. Other participants provide feedback on unit definitions and the original poster revisits their values for constants.

Discussion Status

Participants are actively engaging with the calculations, with some providing clarifications on unit definitions. The original poster acknowledges a mistake in the value of a constant, indicating a productive direction in the discussion.

Contextual Notes

There are indications of confusion regarding the correct values for physical constants and their implications on the calculations. The discussion reflects the challenges of ensuring unit consistency in physics problems.

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Homework Statement


According to statistical mechanics, the average kinetic energy of a particle at temperature T is 3kT/2, where k is the Boltzmann constant. What is the average de Broglie wavelength of nitrogen molecules at room temperature?

Homework Equations


KE = 3kt/2 = p2/2m
λ = h / p

The Attempt at a Solution


So p = (2KEm)1/2, and inserting KE = 3kt/2
p = (3kTm)1/2

And thus λ = h/p = h / (3kTm)1/2

The only problem I have is that it seems like the units don't work out.
Inserting the units only into h / (3kTm)1/2 :

(kg m2 /s2)/((m2 kg/s2 K)(K)(kg))1/2 =
(kg m2 /s2)/(m kg/s) =
m/s, not m

Am I simplifying the units wrong or is the equation wrong?
 
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Your units for h are not quite correct.
 
Ah I see its kg m2 / s. Thanks!
 
I'm having another problem. When I plug the values in where h = 1.602177x10-11 kg m2/s, k = 1.3806488 x 10-23 m2 kg/s2 K, T = 293.15 K, and m = 4.651734 x 10-26 kg/molecule

I get 6.741 x 1011 m when the answer in the book is 0.0276 nm. I'm obviously doing something very wrong.

EDIT: Oop wrong value for h, that explains why several of my answers to different questions were wrong hehe nevermind
 

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