DeBroglie wavelength in infinite potential well

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SUMMARY

The discussion centers on the deBroglie wavelength of an electron in an infinite potential well, specifically for the quantum state n=4. The correct formula for calculating the wavelength is λ = 2L/n. The allowed wavelengths for n=4 are determined to be 3L, 2L, L/2, and L/3, with 3L being identified as the wavelength that is not allowed. The confusion arose from the interpretation of integer multiples of wavelengths, which are essential for valid quantum states.

PREREQUISITES
  • Understanding of quantum mechanics concepts, particularly wave-particle duality.
  • Familiarity with the deBroglie wavelength formula, λ = h/p.
  • Knowledge of infinite potential wells and their implications in quantum physics.
  • Basic grasp of quantum numbers and their significance in determining allowed states.
NEXT STEPS
  • Study the implications of the infinite potential well on quantum states and energy levels.
  • Learn about the significance of quantum numbers in determining allowed wavelengths.
  • Explore the relationship between momentum, wavelength, and energy in quantum mechanics.
  • Investigate the concept of wave functions and their role in quantum state analysis.
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Students of quantum mechanics, physicists, and educators seeking to deepen their understanding of wave-particle duality and the behavior of particles in potential wells.

lowcard2
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nvm i figured it out. it was not in reference to n=4. equation used would be wavelength = 2L/n

Homework Statement


An electron is in an infinite potential well of width L. Which is not an allowed deBroglie wavelength for the electron to have when n=4?
wavelength(k) = 3L, 2L, L/2, or L/3

Homework Equations


k=h/p
would states in an infinite square well be useful too?

The Attempt at a Solution


The answer I was given is 3L which is throwing me off because I thought it would be L/3. there at 2 wavelengths at n=4. 3L= 6 wavelengths which is still integer. I was thinking L/3 because 2/3 is not a valid wavelength. Was the answer i was given wrong or am I doing something wrong?
 
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lowcard2 said:
nvm i figured it out. it was not in reference to n=4. equation used would be wavelength = 2L/n

Homework Statement


An electron is in an infinite potential well of width L. Which is not an allowed deBroglie wavelength for the electron to have when n=4?
wavelength(k) = 3L, 2L, L/2, or L/3


Homework Equations


k=h/p
would states in an infinite square well be useful too?


The Attempt at a Solution


The answer I was given is 3L which is throwing me off because I thought it would be L/3. there at 2 wavelengths at n=4. 3L= 6 wavelengths which is still integer. I was thinking L/3 because 2/3 is not a valid wavelength. Was the answer i was given wrong or am I doing something wrong?

Question is asking that "Which is not an allowed deBroglie wavelength for the electron to have when n=4?"

As you know that de-broglie wavelength is an integral multiple of h/mv.

Here you use formula ,
λ = 2L/n

If electron is excited , then there are infinite number of wavelengths.

If it is de-excited , then there will be only 6 combination of wavelengths ,
4-3,4-2, 4-1, 3-2, 3-1, 2-1.

Now the answer you were given was correct.

Hint : Let h/mv = R

Then ,

λ = R2L/n

2L/n must always be an Integer. In which option it will not be an integer ?
 

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