Density of states arbitrary units

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SUMMARY

The discussion centers on the density of states (DOS) in energy space, specifically in the 3D case, which is defined as the number of states per unit volume per energy, expressed in units of #(number of states)/(cm3 eV). The use of arbitrary units in computational studies of DOS is common, primarily for qualitative analysis, and poses challenges in converting these results to standard units. The conversation highlights that while it is standard practice in computational physics and spectroscopy to report in arbitrary units, this can lead to confusion regarding the actual physical meaning of the results.

PREREQUISITES
  • Understanding of density of states (DOS) in solid-state physics
  • Familiarity with energy units, specifically eV (electronvolts)
  • Basic knowledge of computational simulations in physics
  • Awareness of spectroscopy principles and reporting standards
NEXT STEPS
  • Research methods for converting arbitrary units to standard units in density of states calculations
  • Explore the implications of using arbitrary units in spectroscopy and its effect on data interpretation
  • Study the role of excitation source intensity in spectroscopy and its impact on line intensity reporting
  • Investigate computational techniques for calculating density of states in various materials
USEFUL FOR

Physicists, materials scientists, and researchers involved in computational modeling and analysis of solid-state systems, particularly those interested in the interpretation of density of states and spectroscopy data.

miljohns60
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So the problem is following. The density of states in energy space (3D case) represents the number of states per unit volume per energy. This means that the unit is #(number of states)/(cm^3 eV). This result can be seen in many solid-state physics books.
I am reading some articles where the density of states for different layers is calculated using computer simulations and where the density of states is given in arbitrary units in energy space. What is the meaning of using the arbitrary units for DOS? Shouldn't it be in some form of number of states per unit volume (area or length) per energy? How do I convert that results to #/(cm^3 eV)
 
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miljohns60 said:
What is the meaning of using the arbitrary units for DOS?
They likely were focusing on reporting qualitative features of the DOS. It is a tad annoying; I agree. But it’s pretty standard practice, especially in computational papers.

Another place where you see arbitrary units used frequently is in spectroscopy, where line intensity will generally be reported in arbitrary units unless the paper is specifically reporting absolute oscillator strength. This is because 1) line intensity depends on the intensity of the excitation source, and 2) the most salient features of most spectra (wavelength/frequency, relative intensity between lines, linewidth, etc.) are not related—or are only weakly related—to absolute intensity.
miljohns60 said:
Shouldn't it be in some form of number of states per unit volume (area or length) per energy? How do I convert that results to #/(cm^3 eV)
Yes, it should, and you can’t. There’s no way to know what the units correspond to; they’re arbitrary.
 

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